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| | Pyrrolidine, 2-[diphenyl[(trimethylsilyl)oxy]methyl]-, (2R)- Basic information |
| Product Name: | Pyrrolidine, 2-[diphenyl[(trimethylsilyl)oxy]methyl]-, (2R)- | | Synonyms: | Pyrrolidine, 2-[diphenyl[(trimethylsilyl)oxy]methyl]-, (2R)-;(diphenyl(trimethylsilyloxy)methyl)pyrrolidine;R-Diphenylprolinol trimethyl silyl ether;(2R)-2-[Diphenyl[(trimethylsilyl)oxy]methyl]pyrrolidine;(R)-(+)-a,a-Diphenyl-2-pyrrolidineMethanol TriMethylsilyl Ether;(R)-(+)-alpha,alpha-Diphenyl-2-pyrrolidineMethanol triMethylsilyl ether 96%;(R)-(+)-α,α-Diphenyl-2-pyrrolidineMethanol triMethylsilyl ether 96%;(R)-2-[Diphenyl(trimethylsilanyloxy)methyl]pyrrolidine | | CAS: | 943757-71-9 | | MF: | C20H27NOSi | | MW: | 325.52 | | EINECS: | | | Product Categories: | | | Mol File: | 943757-71-9.mol | ![Pyrrolidine, 2-[diphenyl[(trimethylsilyl)oxy]methyl]-, (2R)- Structure](CAS/GIF/943757-71-9.gif) |
| | Pyrrolidine, 2-[diphenyl[(trimethylsilyl)oxy]methyl]-, (2R)- Chemical Properties |
| Boiling point | 412.7±35.0 °C(Predicted) | | density | 1.021 | | refractive index | n20/D1.5509 | | Fp | >110℃ | | storage temp. | 2-8°C | | pka | 10.01±0.10(Predicted) | | form | clear liquid | | color | Light orange to Yellow to Green | | Optical Rotation | [α]22/D +52±5°, c = 1 in chloroform | | InChI | InChI=1S/C20H27NOSi/c1-23(2,3)22-20(19-15-10-16-21-19,17-11-6-4-7-12-17)18-13-8-5-9-14-18/h4-9,11-14,19,21H,10,15-16H2,1-3H3/t19-/m1/s1 | | InChIKey | RSUHWMSTWSSNOW-LJQANCHMSA-N | | SMILES | N1CCC[C@@H]1C(C1=CC=CC=C1)(C1=CC=CC=C1)O[Si](C)(C)C |
| Hazard Codes | Xi | | Risk Statements | 36/37/38 | | Safety Statements | 26 | | WGK Germany | 3 | | HS Code | 2933.99.8290 | | Storage Class | 11 - Combustible Solids | | Hazard Classifications | Eye Irrit. 2
Skin Irrit. 2
STOT SE 3 |
| | Pyrrolidine, 2-[diphenyl[(trimethylsilyl)oxy]methyl]-, (2R)- Usage And Synthesis |
| Uses | (R)-(+)-α,α-Diphenyl-2-pyrrolidinemethanol trimethylsilyl ether can be used as a catalyst to synthesize:
- Glycofused tricyclic derivatives, which are used in the development of amyloid β-peptide diagnostic tools.
- Cyclohexene carbaldehyde derivatives by reacting benzoylnitromethane with aliphatic enals.
| | General Description | (R)-(+)-α,α-Diphenyl-2-pyrrolidinemethanol trimethylsilyl ether is a diarylprolinol silyl ether organocatalyst. |
| | Pyrrolidine, 2-[diphenyl[(trimethylsilyl)oxy]methyl]-, (2R)- Preparation Products And Raw materials |
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