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(Perfluorobutyl)ethylene

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(Perfluorobutyl)ethylene Basic information
Product Name:(Perfluorobutyl)ethylene
Synonyms:(PERFLUOROBUTYL)ETHYLENE;ZONYL(R) PFBE FLUOROTELOMER INTERMEDIATE;(perfluorobutyl)ethene;1-hexene-3,3,4,4,5,5,6,6,6-nonafluoro;3,3,4,4,5,5,6,6,6-nonafluoro-1-hexen;3,3,4,4,5,5,6,6-nonafluoro-1-hexen;3,3,4,4,5,5,6,6-nonafluoro-1-hexene;3,3,4,4,5,5,6,6,6-nonafluorohexene
CAS:19430-93-4
MF:C6H3F9
MW:246.07
EINECS:243-053-7
Product Categories:Fluorous Chemistry;Fluorous Compounds;Synthetic Organic Chemistry
Mol File:19430-93-4.mol
(Perfluorobutyl)ethylene Structure
(Perfluorobutyl)ethylene Chemical Properties
Boiling point 59-60 °C(lit.)
density 1.452 g/mL at 25 °C(lit.)
vapor density 8.5 (vs air)
vapor pressure 20kPa at 20℃
refractive index n20/D 1.3(lit.)
Fp 1 °F
storage temp. under inert gas (nitrogen or Argon) at 2-8°C
solubility acetone, MEK and trichloroethylene: soluble
form clear liquid
color Colorless to Light yellow to Light red
Specific Gravity1.457
Water Solubility 15.6mg/L at 20℃
BRN 1819716
Henry's Law Constant9.0×10-8 mol/(m3Pa) at 25℃, HSDB (2015)
Exposure limitsACGIH: TWA 100 ppm
InChI1S/C6H3F9/c1-2-3(7,8)4(9,10)5(11,12)6(13,14)15/h2H,1H2
InChIKeyGVEUEBXMTMZVSD-UHFFFAOYSA-N
SMILESFC(F)(F)C(F)(F)C(F)(F)C(F)(F)C=C
LogP4.13
CAS DataBase Reference19430-93-4(CAS DataBase Reference)
EPA Substance Registry System1-Hexene, 3,3,4,4,5,5,6,6,6-nonafluoro- (19430-93-4)
Safety Information
Hazard Codes F
Risk Statements 11
Safety Statements 16-29-33
RIDADR UN 1993 3/PG 2
WGK Germany 3
RTECS MP7360000
Hazard Note Flammable
TSCA TSCA listed
HazardClass 3
PackingGroup II
HS Code 29033990
Storage Class3 - Flammable liquids
Hazard ClassificationsFlam. Liq. 2
Hazardous Substances Data19430-93-4(Hazardous Substances Data)
ToxicityLD orl-rat: >25 g/kg CRTXB2 21,149,90
MSDS Information
ProviderLanguage
1H,1H,2H-Perfluorohex-1-ene English
SigmaAldrich English
ACROS English
ALFA English
(Perfluorobutyl)ethylene Usage And Synthesis
Chemical Properties CLEAR COLOURLESS LIQUID
IUPAC Name: 3,3,4,4,5,5,6,6,6-nonafluorohex-1-ene
Uses1H,1H,2H-Perfluoro-1-hexene is used to generate fluoropolymeers for use in coatings.
ApplicationThe substance (perfluorobutyl)ethylene is used as a co-monomer up to 0.09% w/w in producing polytetrafluoroethylene (PTFE) polymers processed at high temperatures. Examples of intended uses are coated cookware, such as coatings on frying pans and articles for oven baking, and moulded articles for industrial use.
Cytotoxicity (Perfluorobutyl)ethylene (also known as Perfluorobutyl ethlene) was examined for its potential to induce reverse mutations in bacteria, forward mutations at the thymidine kinase (tk) locus in mouse lymphoma L5178Y cells, and structural chromosomal aberrations in Chinese Hamster Ovary (CHO) cells. Negative results were obtained in adequate studies, both in absence and presence of exogenous metabolic activation. Therefore, (perfluorobutyl)ethylene is considered non-genotoxic.
Safety ProfileLow toxicity by ingestion andinhalation routes. When heated to decomposition it emitstoxic vapors of Fí.
Toxics Screening LevelThe initial threshold screening level (ITSL) for Perfluorobutylethylene (PFBE) is 10,000 μg/m3 based on an 8-hour averaging time. The ITSL for the annual averaging time is 2,600 μg/m3.
(Perfluorobutyl)ethylene Preparation Products And Raw materials
Preparation ProductsNonafluoropentanal hydrate
Tag:(Perfluorobutyl)ethylene(19430-93-4) Related Product Information
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