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Tetrakis(triphenyl phosphite)nickel(0)

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Tetrakis(triphenyl phosphite)nickel(0) Basic information
Product Name:Tetrakis(triphenyl phosphite)nickel(0)
Synonyms:[(PhO)3P]4Ni;Nickel tetrakis(triphenoxyphosphine);Tetrakis(triphenoxyphosphine)nickel;Tetrakis(triphenyl phosphite)nickel;tetrakis(triphenyl phosphite)nickel(O);Tetrakis(triphenyl phosphite)nickel(0),95%;TETRAKIS(TRIPHENYL PHOSPHITE)NICKEL(0) ISO 9001：2015 REACH;nickel,triphenylphosphite
CAS:14221-00-2
MF:C72H60NiO12P4
MW:1299.83
EINECS:
Product Categories:Catalysis and Inorganic Chemistry;Chemical Synthesis
Mol File:14221-00-2.mol
Tetrakis(triphenyl phosphite)nickel(0) Structure
Tetrakis(triphenyl phosphite)nickel(0) Chemical Properties
Melting point 145 °C (dec.)(lit.)
storage temp. 2-8°C
solubility sol THF, toluene.
form solid
InChIInChI=1S/4C18H15O3P.Ni/c4*1-4-10-16(11-5-1)19-22(20-17-12-6-2-7-13-17)21-18-14-8-3-9-15-18;/h4*1-15H;
InChIKeyPGXCIAAANFTEKX-UHFFFAOYSA-N
SMILES[Ni].O(P(Oc1ccccc1)Oc2ccccc2)c3ccccc3.O(P(Oc4ccccc4)Oc5ccccc5)c6ccccc6.O(P(Oc7ccccc7)Oc8ccccc8)c9ccccc9.O(P(Oc%10ccccc%10)Oc%11ccccc%11)c%12ccccc%12
EPA Substance Registry SystemNickel, tetrakis(triphenyl phosphite-.kappa.P)-, (T-4)- (14221-00-2)
Safety Information
Hazard Codes Xn
Risk Statements 36/37/38-40-43
Safety Statements 26-36/37
WGK Germany 3
TSCA TSCA listed
HS Code 29209090
Storage Class11 - Combustible Solids
Hazard ClassificationsCarc. 2
Eye Irrit. 2
Skin Irrit. 2
Skin Sens. 1
STOT SE 3
MSDS Information
ProviderLanguage
SigmaAldrich English
ACROS English
Tetrakis(triphenyl phosphite)nickel(0) Usage And Synthesis
Chemical Propertieswhite to off-white powder
UsesCatalyst for alkene and alkyne hydrocyanation and styrenedimerization
PreparationTetrakis(triphenyl phosphite)nickel(0) can be prepared by treating Nickel(II) Acetylacetonate with Sodium Borohydride and Triphenyl Phosphite.[1]
reaction suitabilitycore: nickel
reagent type: catalyst
storageTetrakis(triphenyl phosphite)nickel(0) is a cancer suspect agent; is air sensitive and should be handled using Schlenk or glove-box techniques.
References1. McLaughlin, J. R. Inorg. Nucl. Chem. Lett. 1973, 9, 565.
Tetrakis(triphenyl phosphite)nickel(0) Preparation Products And Raw materials
Tag:Tetrakis(triphenyl phosphite)nickel(0)(14221-00-2) Related Product Information
Tetrakis(triphenyl phosphite)nickel(0) Methyl diphenylphosphite Triphenyl phosphate Trimethyl phosphite Nickel sulfate hexahydrate tetrakis(tritolyl phosphite )nickel Triphenyl phosphite