(S)-2'-Amino-1,1'-binaphthalen-2-ol manufacturers
|
| | (S)-2'-Amino-1,1'-binaphthalen-2-ol Basic information |
| Product Name: | (S)-2'-Amino-1,1'-binaphthalen-2-ol | | Synonyms: | (S)-(+)-2-AMINO-2''-HYDROXY-1,1''-BINAPHTHYL / S-NOBIN;(S)-(-)-NOBIN 99%;(S)-(-)-2-AMINO-2'-HYDROXY-1 1'-BINAPHT;S)-(-)-2-Amino-2'-Hydroxy-1,1'-Binaphthol;S-2'-Amino-1,1'-binaphthalen-2-ol, S-NOBIN;1-(2-aMinonaphthalen-1-yl)naphthalen-2-ol;(S)-(-)-1-(2-Amino-1-naphthyl)-2-naphthol
(S)-(-)-NOBIN
(S)-(-)-2'-Amino-1,1'-binaphthalen-2-ol;(S)-(-)-2-Amino-2'-hydroxy-1,1'-binaphthalene | | CAS: | 137848-29-4 | | MF: | C20H15NO | | MW: | 285.34 | | EINECS: | | | Product Categories: | Auxiliaries,Catalysts;chiral;CHIRAL COMPOUNDS | | Mol File: | 137848-29-4.mol |  |
| | (S)-2'-Amino-1,1'-binaphthalen-2-ol Chemical Properties |
| Melting point | 171.0 to 175.0 °C | | Boiling point | 471.5±30.0 °C(Predicted) | | density | 1.275 | | storage temp. | Keep in dark place,Inert atmosphere,Room temperature | | form | powder to crystal | | pka | 8.90±0.50(Predicted) | | color | White to Light red to Green | | InChI | 1S/C20H15NO/c21-17-11-9-13-5-1-3-7-15(13)19(17)20-16-8-4-2-6-14(16)10-12-18(20)22/h1-12,22H,21H2 | | InChIKey | HIXQCPGXQVQHJP-UHFFFAOYSA-N | | SMILES | Nc1c(c4c(cc1)cccc4)c2c3c(ccc2O)cccc3 | | CAS DataBase Reference | 137848-29-4(CAS DataBase Reference) |
| Hazard Codes | Xi,N | | Risk Statements | 36/37/38-50/53-41 | | Safety Statements | 26-36/37/39-61-60-39 | | RIDADR | UN 3077 9 / PGIII | | WGK Germany | 3 | | HS Code | 29222990 | | Storage Class | 11 - Combustible Solids | | Hazard Classifications | Aquatic Acute 1
Aquatic Chronic 1
Eye Dam. 1 |
| | (S)-2'-Amino-1,1'-binaphthalen-2-ol Usage And Synthesis |
| Chemical Properties | Red crystal | | Uses | (S)-(-)-2′-Amino-1,1′-binaphthalen-2-ol or (S)-NOBIN, is a non-symmetrically substituted 1,1′-binaphthalene ligand. It can be used as a catalyst in the asymmetric synthesis of unnatural α-alkyl amino acids by phase-transfer catalysis (PTC). (S)-NOBIN can also be employed as starting material to prepare N-monoalkyl and N,N-dialkyl (S)-NOBIN analogs by reacting with aldehydes via reductive amination reaction. N-monoaryl derivatives are obtained from NOBIN via HartwigBuchwald arylation reaction. |
| | (S)-2'-Amino-1,1'-binaphthalen-2-ol Preparation Products And Raw materials |
|