PCN-250(Fe)金属有机骨架
| 中文名称 | PCN-250(Fe)金属有机骨架 |
|---|---|
| 中文同义词 | 铁偶氮苯四羧酸,多孔[PCN-250(FE)], F250;PCN-250(FE)金属有机骨架 |
| 英文名称 | Iron azobenzene tetracarboxylic, Porous [PCN-250(Fe)], CONEKTIC(TM) F250 |
| 英文同义词 | IRONAZOBENZENETETRACARBOXYLIC,POROUS[PCN-250(FE)],CONEKTIC F250;Iron azobenzene tetracarboxylic, Porous [PCN-250(Fe)], CONEKTIC(TM) F250;MOF:PCN-250(FE);Iron azobenzene tetracarboxylic, Porous [PCN-250(Fe)], AYRSORB F250;Iron azobenzene tetracarboxylic, Porous [PCN-250(Fe)] |
| CAS号 | 1771755-22-6 |
| 分子式 | C48H28Fe6N6O32 |
| 分子量 | 1535.82692 |
| EINECS号 | |
| 相关类别 | MOF |
| Mol文件 | 1771755-22-6.mol |
| 结构式 |  |
PCN-250(Fe)金属有机骨架 性质
| 形态 | 粉末 |
|---|---|
| 颜色 | 深红棕色 |
| 配位金属 | Fe |
| 配体 | 3,3’,5,5’-azobenzenetetracarboxylic（CAS：365549-33-3） |
| 孔径 | 1nm |
| 孔容 | 0.5cm3/g |
| 比表面 | BET比表面1200-1400m2/g |
参考文献
[1] Kinetically tuned dimensional augmentation as a versatile synthetic route towards robust metal–organic frameworks. https://doi.org/10.1038/ncomms6723
[2] Iron(iii) metal–organic frameworks as solid Lewis acids for the isomerization of α-pinene oxide. https://doi.org/10.1039/C2CY00376G
[3] Maintaining the configuration of a light-responsive metal-organic framework: LiYGeO₄:Bi³⁺-incorporation-induced long-term bending through short-time light irradiation. https://doi.org/10.1039/d3ta01241g
[4] Iron-Based Metal-Organic Frameworks (MOF) as Photocatalysts for Radical and Cationic Polymerizations under Near UV and Visible LEDs (385–405 nm). https://doi.org/10.1002/macp.201600352
[5] Water-Based Synthesis of a Stable Iron-Based Metal−Organic Framework for Capturing Toxic Gases. https://doi.org/10.1021/acsmaterialslett.0c00264