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DIMETHYLPHOSPHORAMIDOUS DICHLORIDE

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DIMETHYLPHOSPHORAMIDOUS DICHLORIDE manufacturers
DIMETHYLPHOSPHORAMIDOUS DICHLORIDE Basic information
Product Name:DIMETHYLPHOSPHORAMIDOUS DICHLORIDE
Synonyms:Dimethylphosphoramidous dichloride,97%;N,N-Dimethylamide phosphorous aciddichloride;DICHLORO(DIMETHYLAMINO)PHOSPHINE;(DIMETHYLAMINO)PHOSPHONOUS DICHLORIDE;DIMETHYLAMINOPHOSPHOROUS DICHLORIDE;DIMETHYLAMINOPHOSPHORUS DICHLORIDE;DIMETHYLPHOSPHORAMIDOUS DICHLORIDE;Dichlor(dimethylamino)phosphan
CAS:683-85-2
MF:C2H6Cl2NP
MW:145.96
EINECS:
Product Categories:Phosphorus Compounds;Phosphorus Halides;Organic Building Blocks
Mol File:683-85-2.mol
DIMETHYLPHOSPHORAMIDOUS DICHLORIDE Structure
DIMETHYLPHOSPHORAMIDOUS DICHLORIDE Chemical Properties
Boiling point 150 °C (lit.)
density 1.271 g/mL at 25 °C (lit.)
refractive index n20/D 1.505(lit.)
Fp −10 °F
storage temp. 2-8°C
form Liquid
pka-1.98±0.70(Predicted)
color Colorless to light yellow
Water Solubility Reacts with water.
Sensitive Moisture Sensitive
InChIInChI=1S/C2H6Cl2NP/c1-5(2)6(3)4/h1-2H3
InChIKeyXPWWDZRSNFSLRQ-UHFFFAOYSA-N
SMILESP(N(C)C)(Cl)Cl
CAS DataBase Reference683-85-2(CAS DataBase Reference)
Safety Information
Hazard Codes F,C
Risk Statements 11-14-34
Safety Statements 16-23-26-27-36/37/39-45
RIDADR UN 2924 3/PG 2
WGK Germany 3
HazardClass 3
PackingGroup II
HS Code 29310099
Storage Class3 - Flammable liquids
Hazard ClassificationsEye Dam. 1
Flam. Liq. 2
Skin Corr. 1B
MSDS Information
ProviderLanguage
SigmaAldrich English
ACROS English
DIMETHYLPHOSPHORAMIDOUS DICHLORIDE Usage And Synthesis
Chemical PropertiesColorless to light yellow liquid
UsesDimethylphosphoramidous dichloride (N,N-dimethylamidodichlorophosphite) may be used in the synthesis of the following N,N-dimethylamidotetrachlorophosphorane, O-propylchloroformimino-N,N-dimethylamidochlorophosphate, bisarylsulphonyldiazadiphosphetidines.
UsesDimethylphosphoramidous dichloride (N,N-dimethylamidodichlorophosphite) may be used in the synthesis of the following:
  • N,N-dimethylamidotetrachlorophosphorane
  • O-propylchloroformimino-N,N-dimethylamidochlorophosphate
  • 1,3-bisarylsulphonyl-1,3,2,4-diazadiphosphetidines
General DescriptionDimethylphosphoramidous dichloride (dimethylaminodichlorophosphine) is a phosphorus chloride derivative. It exists in two stable isomers, a gauche-conformer with C1 symmetry and anti-conformer with Cs symmetry. Its synthesis has been reported. Molecular conformation has been investigated through correlation between the 35Cl NQR frequencies and charge on the chlorine atoms. Its vibrational spectra has been studied. Its reaction with SO2 has been investigated. It participates in the synthesis of [(dimethylamino)phosphoryl] bis(difluoromethylene)phosphonate.
Tag:DIMETHYLPHOSPHORAMIDOUS DICHLORIDE(683-85-2) Related Product Information
DIETHYLPHOSPHORAMIDOUS DICHLORIDE DIISOPROPYLPHOSPHORAMIDOUS DICHLORIDE AURORA KA-1196 DIMETHYLPHOSPHORAMIDOUS DICHLORIDE AURORA KA-1777 DI-CHLORO N,N-DIISOPROPYLPHOSPHORAMIDITE DICHLORO N,N-DIETHYLPHOSPHORAMIDITE N,N-DIMETHYLPHOSPHORAMIDODICHLORIDATE DIALLYLAMINODICHLOROPHOSPHINE AURORA KA-1193 AURORA KA-1672