5',5'''-双(4-羧基苯基)-5''-(4,4''-二羧基-[1,1':3',1''-三联苯]-5'-基)-[1,1':3',1'':3'',1''':3''',1''''-五苯基]-4,4''''-二羧酸
| 中文名称 | 5',5'''-双(4-羧基苯基)-5''-(4,4''-二羧基-[1,1':3',1''-三联苯]-5'-基)-[1,1':3',1'':3'',1''':3''',1''''-五苯基]-4,4''''-二羧酸 |
|---|---|
| 中文同义词 | 5',5'''-双(4-羧基苯基)-5''-(4,4''-二羧基-[1,1':3',1''-三联苯]-5'-基)-[1,1':3',1'':3'',1''':3''',1''''-五苯基]-4,4''''-二羧酸;5',5'''-双(4-羧基苯基)-5''-(4,4''-二羧基-[1,1':3',1''-三联苯]-5'-基)-[1,1':3',1'':3'',1''':3''',1''''-五苯基]-4,4'';5',5'''-双(4-羧基苯基)-5''-(4,4''-二羧基-[1,1':3',1''-三联苯]-5'-基)-[1,1':3',1'':3'',1''':3''',1''''-五联苯]-4,4''''-二甲酸;quinquephenyl]-4,4''''-dicarboxylic acid |
| 英文名称 | 5',5'''-bis(4-carboxyphenyl)-5''-(4,4''-dicarboxy[1,1':3',1''-terphenyl]-5'-yl)-[1,1':3',1'':3'',1''':3''',1''''-Quinquephenyl]-4,4''''-dicarboxylic acid |
| 英文同义词 | [1,1':3',1'':3'',1''':3''',1''''-Quinquephenyl]-4,4''''-dicarboxylic acid, 5',5'''-bis(4-carboxyphenyl)-5''-(4,4''-dicarboxy[1,1':3',1''-terphenyl]-5'-yl)-;[1,1':3',1'':3'',1''':3''',1''''-QUINQUEPHENYL]-4,4''''-DICARBOXYLICACID,5',5'''-BIS(4-CARBOXYPHENYL;5',5'''-bis(4-carboxyphenyl)-5''-(4,4''-dicarboxy[1,1':3',1''-terphenyl]-5'-yl)-[1,1':3',1'':3'',1''':3''',1''''-Quinquephenyl]-4,4''''-dicarboxylic acid;4-[3-[3,5-Bis[3,5-bis(4-carboxyphenyl)phenyl]phenyl]-5-(4-carboxyphenyl)phenyl]benzoic acid;5',5'''-bis(4-carboxyphenyl)-5''-(4,4''-dicarboxy[1,1':3',1''-terphenyl]-5'-yl)...;1,3,5-Tris(3,5-di(4-carboxyphenyl)phenyl)benzene;5',5'''-Bis(4-carboxyphenyl)-5''-(4,4''-dicarboxy-[1,1':3',1''-terphenyl]-5'-yl)-[1,1':3',1'':3'',1''':3''',1''''-quinquephenyl]-4,4''''-dicarboxylic acid;1,3,5-tris(3,5-di(4-carboxy-phenyl-1-yl)phenyl-1-yl)benzene |
| CAS号 | 1331745-95-9 |
| 分子式 | C66H42O12 |
| 分子量 | 1027.03 |
| EINECS号 | |
| 相关类别 | 有机化学;科研材料中间体 |
| Mol文件 | 1331745-95-9.mol |
| 结构式 | ![5',5'''-双(4-羧基苯基)-5''-(4,4''-二羧基-[1,1':3',1''-三联苯]-5'-基)-[1,1':3',1'':3'',1''':3''',1''''-五苯基]-4,4''''-二羧酸 结构式](CAS/20210111/GIF/1331745-95-9.gif) |
5',5'''-双(4-羧基苯基)-5''-(4,4''-二羧基-[1,1':3',1''-三联苯]-5'-基)-[1,1':3',1'':3'',1''':3''',1''''-五苯基]-4,4''''-二羧酸 性质
| 密度 | 1.365±0.06 g/cm3(Predicted) |
|---|---|
| 储存条件 | Store at room temperature |
| 酸度系数(pKa) | 3.12±0.10(Predicted) |
| 外观 | 白色至灰白色固体 |
| InChIKey | LPKOYHKLQPVBEA-UHFFFAOYSA-N |
5',5'''-双(4-羧基苯基)-5''-(4,4''-二羧基-[1,1':3',1''-三联苯]-5'-基)-[1,1':3',1'':3'',1''':3''',1''''-五苯基]-4,4''''-二羧酸 用途与合成方法
可作为配体用于合成MOF材料：JUC-100;UTSA-61/62
[2] A mesoporous lanthanide–organic framework constructed from a dendritic hexacarboxylate with cages of 2.4 nm. https://doi.org/10.1039/C3CE41062E
[3] Low-energy regeneration and high productivity in a lanthanide–hexacarboxylate framework for high-pressure CO2–CH4–H2 separation. https://doi.org/10.1039/C3CC43196G
参考文献
[1] A novel low density metal–organic framework with pcu topology by dendritic ligand. https://doi.org/10.1039/C1CC12891D
[2] A mesoporous lanthanide–organic framework constructed from a dendritic hexacarboxylate with cages of 2.4 nm. https://doi.org/10.1039/C3CE41062E
[3] Low-energy regeneration and high productivity in a lanthanide–hexacarboxylate framework for high-pressure CO2–CH4–H2 separation. https://doi.org/10.1039/C3CC43196G