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Phenylmagnesium chloride

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Phenylmagnesium chloride Basic information
Product Name:Phenylmagnesium chloride
Synonyms:PHENYLMAGNESIUM CHLORIDE, 2.0M SOLUTION IN TETRAHYDROFURAN;PHENYLMAGNESIUM CHLORIDE 25 WT% IN THF;Phenylmagnesium chloride, 25 wt% solution in tetrahydrofuran;PHENYLMAGNESIUM CHLORIDE, 1 M in DIBUTYL ETHER;PHENYLMAGNESIUM CHLORIDE, 2 M in TETRAHYDROFURAN;Phenylmagnesiumchloride,2-3MinTHF;PHENYLMAGNESIUMCHLORIDE,25%INTETRAHYDROFURAN;Chlorphenylmagnesium
CAS:100-59-4
MF:C6H5ClMg
MW:136.86
EINECS:202-868-8
Product Categories:Organometallics;Classes of Metal Compounds;Grignard Reagents;Grignard Reagents & Alkyl Metals;Mg (Magnesium) Compounds;Synthetic Organic Chemistry;Typical Metal Compounds;Aryl;Grignard Reagents;Organometallic Reagents;grignard reagent
Mol File:100-59-4.mol
Phenylmagnesium chloride Structure
Phenylmagnesium chloride Chemical Properties
Melting point 89-90℃
Boiling point 230℃ (8 Torr)
density 0.98 g/mL at 20 °C
Fp 1 °F
storage temp. 2-8°C
form solution
color Yellow
Water Solubility It reacts violently with water.
Sensitive Air & Moisture Sensitive
Merck 14,7298
BRN 3587900
InChIInChI=1S/C6H5.ClH.Mg/c1-2-4-6-5-3-1;;/h1-5H;1H;/q;;+1/p-1
InChIKeyGQONLASZRVFGHI-UHFFFAOYSA-M
SMILESC1([Mg]Cl)C=CC=CC=1
CAS DataBase Reference100-59-4(CAS DataBase Reference)
EPA Substance Registry SystemMagnesium, chlorophenyl- (100-59-4)
Safety Information
Hazard Codes F,C
Risk Statements 14-19-20/21/22-34-67-65-63-48/20-11-40-37
Safety Statements 26-36/37/39-45-62-33-16
RIDADR UN 2924 3/PG 2
WGK Germany 2
F 10
TSCA TSCA listed
HazardClass 8
PackingGroup II
HS Code 29319090
Storage Class3 - Flammable liquids
Hazard ClassificationsCarc. 2
Eye Dam. 1
Flam. Liq. 2
Skin Corr. 1B
STOT SE 3
Hazardous Substances Data100-59-4(Hazardous Substances Data)
MSDS Information
ProviderLanguage
SigmaAldrich English
ACROS English
Phenylmagnesium chloride Usage And Synthesis
Chemical Propertiesyellowish-brown to dark brown solution
UsesIn organic synthesis, especially in the production of hydrocarbons, alcohols, ketones, organic acids, amines, silicones, boranes.
UsesGrignard reagent in greener solvent, 2-methyltetrahydrofuran (2-MeTHF)

2-Methyltetrahydrofuran (2-MeTHF): A Biomass-Derived Solvent with Broad Application in Organic Chemistry
UsesPhenylmagnesium chloride (PhMgCl) solution is a common Grignard reagent used in the synthesis of ()-phenserine and stephacidin B. It is employed in a variety of cross-coupling reactions. It can also be used as an electrolyte solution along with aluminium chloride (AlCl3) in the rechargeable magnesium batteries.
DefinitionChEBI: Phenylmagnesium chloride is an arylmagnesium halide.
General DescriptionThis product has been enhanced for energy efficiency.
reaction suitabilityreaction type: Grignard Reaction
Tag:Phenylmagnesium chloride(100-59-4) Related Product Information
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