Ethyl 5-amino-4-phenylisoxazole-3-carboxylate

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Ethyl 5-amino-4-phenylisoxazole-3-carboxylate Basic information
Product Name:Ethyl 5-amino-4-phenylisoxazole-3-carboxylate
Synonyms:5-amino-4-phenyl-3-Isoxazolecarboxylic acid ethyl ester;3-Isoxazolecarboxylic acid, 5-amino-4-phenyl-, ethyl ester;Ethyl 5-amino-4-phenyl-3-isoxazolecarboxylate;ethyl 5-amino-4-phenyl-1,2-oxazole-3-carboxylate
CAS:53983-15-6
MF:C12H12N2O3
MW:232.24
EINECS:
Product Categories:
Mol File:53983-15-6.mol
Ethyl 5-amino-4-phenylisoxazole-3-carboxylate Structure
Ethyl 5-amino-4-phenylisoxazole-3-carboxylate Chemical Properties
storage temp. 2-8°C(protect from light)
Safety Information
MSDS Information
Ethyl 5-amino-4-phenylisoxazole-3-carboxylate Usage And Synthesis
Synthesis
Benzenepropanoic acid, β-methyl-, ethyl ester, (βS)-

1134-71-0

Ethyl 5-amino-4-phenylisoxazole-3-carboxylate

53983-15-6

General procedure for the synthesis of ethyl 5-amino-4-phenylisoxazole-3-carboxylate from the compound (CAS: 1134-71-0): phenylpropyl derivative 1 (12 mmol), hydroxylamine hydrochloride (1.66 g, 24 mmol) and 70 mL of ethanol were mixed and heated and refluxed for 12 hours. Upon completion of the reaction, the ethanol was removed by distillation under reduced pressure. Subsequently, 50 mL of ethyl acetate and 10 mL of 10% sodium carbonate solution were added to the residue and mixed thoroughly to separate the organic phase. The organic phase was washed with saturated sodium chloride solution and dried with anhydrous sodium sulfate. Finally, the ethyl acetate was removed by evaporation under reduced pressure to give 2.48 g of white powdery solid product in 89.11% yield.

References[1] Patent: CN105777661, 2016, A. Location in patent: Paragraph 0041; 0042; 0043
Ethyl 5-amino-4-phenylisoxazole-3-carboxylate Preparation Products And Raw materials
Raw materialsALPHA-METHYLPHENYLACETONITRILE-->Benzenepropanoic acid, β-methyl-, ethyl ester, (βS)--->Ethanol-->Hydroxylamine hydrochloride
Tag:Ethyl 5-amino-4-phenylisoxazole-3-carboxylate(53983-15-6) Related Product Information
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