(S)-(+)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-a

(S)-(+)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-a Suppliers list
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(S)-(+)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-a Basic information
Reactions
Product Name:(S)-(+)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-a
Synonyms:3,4-a']dinaphthalen-4-yl)morpholine,min.97%(S)-MorfPhos;(S)-(+)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-a:3,4-a']dinaphthalen-4-yl)morpholine, min. 97% (S)-MorfPhos;97% (S)-MorfPhos;(S)-4-(Dinaphtho[2,1-d:1',2'-f][1,3,2]-dioxaphosphepin-4-yl)morpholine;4-(11bS)-Dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-ylmorpholine;4-(11bS)-Dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin- 4-ylmorpholine,99%e.e.;3,4-a']dinaphthalen-4-yl)Morpholine (S)-MorfPhos;(S)-MorfPhos
CAS:185449-81-4
MF:C24H20NO3P
MW:401.39
EINECS:
Product Categories:Chiral Phosphine;CPN
Mol File:185449-81-4.mol
(S)-(+)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-a Structure
(S)-(+)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-a Chemical Properties
Boiling point 613.7±65.0 °C(Predicted)
storage temp. under inert gas (nitrogen or Argon) at 2-8°C
pka-0.88±0.20(Predicted)
form Powder
color white
Sensitive moisture sensitive
Safety Information
MSDS Information
(S)-(+)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-a Usage And Synthesis
Reactions1. Ligand used in the enantioselective rhodium catalyzed low pressure high activity hydrogenation of α–dehydroaminoesters, enamides, and dimethylitaconate.
2. Ligand used in iridinium-catalyzed asymmetric hydrogenation of 2-methylindole.
Reactions of 185449-81-4
(S)-(+)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-a Preparation Products And Raw materials
Tag:(S)-(+)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-a(185449-81-4) Related Product Information
(S)-(-)-2,2'-Bis(di-p-tolylphosphino)-1,1'-binaphthyl Morpholinazole (S)-(+)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-a (S)-(-)-2,2'-Bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl (S)-(-)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl (S)-(+)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-a (R)-MONOPHOS (S)-(+)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-a