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| | Titanium ethoxide Basic information |
| | Titanium ethoxide Chemical Properties |
| Melting point | 54°C | | Boiling point | 150-152 °C10 mm Hg(lit.) | | density | 1.088 g/mL at 25 °C(lit.) | | vapor pressure | 57.26hPa at 19.6℃ | | refractive index | n20/D 1.505(lit.) | | Fp | 84 °F | | storage temp. | 2-8°C | | solubility | Soluble in organic solvents. | | form | Liquid | | color | Pale yellow | | Specific Gravity | 1.107 (20℃) | | Water Solubility | reacts | | Sensitive | Moisture Sensitive | | BRN | 3678992 | | Exposure limits | ACGIH: TWA 200 ppm; STEL 400 ppm
OSHA: TWA 400 ppm(980 mg/m3)
NIOSH: IDLH 2000 ppm; TWA 400 ppm(980 mg/m3); STEL 500 ppm(1225 mg/m3) | | Stability: | Stability Incompatible with strong oxidizing agents, strong acids. May decompose upon exposure to air or moisture. | | Cosmetics Ingredients Functions | BINDING | | InChI | 1S/4C2H5O.Ti/c4*1-2-3;/h4*2H2,1H3;/q4*-1;+4 | | InChIKey | JMXKSZRRTHPKDL-UHFFFAOYSA-N | | SMILES | CCO[Ti](OCC)(OCC)OCC | | LogP | -0.3 at 25℃ | | CAS DataBase Reference | 3087-36-3(CAS DataBase Reference) | | NIST Chemistry Reference | Ti(OEt)4(3087-36-3) | | EPA Substance Registry System | Ethanol, titanium(4+) salt (3087-36-3) |
| Hazard Codes | Xi | | Risk Statements | 10-36/37/38-67 | | Safety Statements | 26-37/39-16 | | RIDADR | UN 1993 3/PG 3 | | WGK Germany | 3 | | F | 3-10-21 | | TSCA | TSCA listed | | HazardClass | 4.1 | | PackingGroup | III | | HS Code | 29051900 | | Storage Class | 3 - Flammable liquids | | Hazard Classifications | Eye Irrit. 2
Flam. Liq. 3 |
| | Titanium ethoxide Usage And Synthesis |
| Chemical Properties | colourless liquid | | Uses | Titanium(IV) ethoxide is used in organic synthesis and material science. It is involved in the synthesis of anti-perspirants and antifungal agents. Furthermore, it is used to prepare carbon films in association with silicon dioxide. It is also used as a precursor for the synthesis of Ti4+ ions titanium nanoparticles by various methods. | | Uses | Titanium ethoxide is used widely as a precursor for the synthesis of Ti4+ ions titania nanoparticles by various techniques such as :
- in the sol-gel synthesis of free-standing ferroelectric lead zirconate titanate nanoparticles
- spherical titania cores, produced either by hydrolysis of Ti(IV) ethoxide droplets in contact with water vapor or
- by preadsorption of the titanium alkoxides into/onto the clay mineral platelets and their subsequent hydrolysis and calcination.
| | Uses | Titanium(IV) ethoxide can be used:
- As an activator and dehydrating agent for by condensation of (S)-(+)-p-toluenesulfinamide with aldehydes and ketones to form sulfinimines.
- As a Ti4+ ion source to form complexes of titanium (IV) acrylate with methacrylic acid.
- As a catalyst to synthesize esters of sterically hindered alcohols via transesterification reactions.
| | Application | Titanium(IV) ethoxide can be used:
As an activator and dehydrating agent for by condensation of (S)-(+)-p-toluenesulfinamide with aldehydes and ketones to form sulfinimines.
As a Ti4+ ion source to form complexes of titanium (IV) acrylate with methacrylic acid.
As a catalyst to synthesize esters of sterically hindered alcohols via transesterification reactions. | | Flammability and Explosibility | Flammable | | reaction suitability | core: titanium
reagent type: catalyst | | Materials Uses | Titanium ethoxide is used widely as a precursor for the synthesis of Ti4+ ions titania nanoparticles by various techniques such as :
in the sol-gel synthesis of free-standing ferroelectric lead zirconate titanate nanoparticles
spherical titania cores, produced either by hydrolysis of Ti(IV) ethoxide droplets in contact with water vapor or
by preadsorption of the titanium alkoxides into/onto the clay mineral platelets and their subsequent hydrolysis and calcination. |
| | Titanium ethoxide Preparation Products And Raw materials |
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