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| | CERIUM(IV) TRIFLUOROMETHANESULFONATE Basic information |
| Product Name: | CERIUM(IV) TRIFLUOROMETHANESULFONATE | | Synonyms: | CERIUM(IV) TRIFLATE;CERIUM(IV) TRIFLUOROMETHANESULFONATE;CERIUM(IV) TRIFLUOROMETHANESULPHONATE;ceric triflate;Cerium(IV) trifluoromethanesulfonate,99%;CeriuM(IV) trifluoroMethanesulfonate, Ce(CF3SO3)4 | | CAS: | 107792-63-2 | | MF: | C4CeF12O12S4 | | MW: | 736.39 | | EINECS: | 000-000-0 | | Product Categories: | | | Mol File: | 107792-63-2.mol |  |
| | CERIUM(IV) TRIFLUOROMETHANESULFONATE Chemical Properties |
| solubility | soluble in DMSO | | form | Solid | | color | Yellow | | Water Solubility | Soluble in water. | | Sensitive | Hygroscopic |
| Hazard Codes | C | | Risk Statements | 34 | | Safety Statements | 45-36/37/39-26 | | TSCA | No | | HS Code | 29310099 |
| | CERIUM(IV) TRIFLUOROMETHANESULFONATE Usage And Synthesis |
| Chemical Properties | Cerium(IV) Trifluoromethanesulfonate (ceric triflate) is a oxidizing agent for benzyl alcohols and toluenes; yellow powder or solid; sol water, THF, DME, dioxane; insol dichloromethane, hexane, benzene. | | Uses | Cerium(IV) trifluoromethanesulfonate, is used as a strong oxidizing agent, in the oxidation of benzyl alcohols and alkylbenzenes to aryl aldehydes and aryl ketones respectively. It can also be used as a catalyst for high-yield deprotection of tert-butyldimethylsilyl ethers | | Preparation | By the reaction of trifluoromethanesulfonic acid with freshly prepared
cerium(IV) carbonate[1]. Cerium(IV) Trifluoromethanesulfonate can be prepared in situ by the electrochemical oxidation of
Ce(OTf)3 in aqueous trifluoromethanesulfonic acid[2]. | | storage | Cerium(IV) trifluoromethanesulfonate is extremely hygroscopic and should be
stored under strict absence of moisture. This reagent should be handled in a fume hood. | | References | 1. Imamoto, T.; Koide, Y.; Hiyama, S. CL 1990, 1445.
2. Kreh, R. P.; Spotnitz, R. M.; Lundquist, J. T. TL 1987, 28, 1067. |
| | CERIUM(IV) TRIFLUOROMETHANESULFONATE Preparation Products And Raw materials |
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