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12-[1-L (E)-hexenyloxy]-9(Z),11(E)-dodecadienoic acid

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12-[1-L (E)-hexenyloxy]-9(Z),11(E)-dodecadienoic acid Basic information
Product Name:12-[1-L (E)-hexenyloxy]-9(Z),11(E)-dodecadienoic acid
Synonyms:ETHEROLEIC ACID;12-[1-L (E)-hexenyloxy]-9(Z),11(E)-dodecadienoic acid
CAS:169217-38-3
MF:C18H30O3
MW:294.43
EINECS:
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Mol File:Mol File
12-[1-L (E)-hexenyloxy]-9(Z),11(E)-dodecadienoic acid Structure
12-[1-L (E)-hexenyloxy]-9(Z),11(E)-dodecadienoic acid Chemical Properties
Boiling point 402.483±18.00 °C(Press: 760.00 Torr)(predicted)
density 0.958±0.06 g/cm3(Temp: 25 °C; Press: 760 Torr)(predicted)
solubility Ethanol: soluble
pka4.776±0.10(predicted)
Safety Information
MSDS Information
12-[1-L (E)-hexenyloxy]-9(Z),11(E)-dodecadienoic acid Usage And Synthesis
DescriptionEtheroleic acid is a divinyl ether oxylipin.1,2 It is a metabolite of linolenic acid that is formed in plants via 13-lipoxygenase-mediated formation of 13(S)-HpODE or (±)13-HpODE followed by conversion to the divinyl ether by divinyl ether synthase. Etheroleic acid (30 μM) is fungicidal against the powdery mildew B. graminis on the second leaves of barley seedlings.3
UsesEtheroleic acid has antifungal activity against the powdery mildew B. graminis on the second leaves of barley seedlings. Etheroleic acid is a metabolite of Linolenic acid[1].
References1. Grechkin, A.N., Ilyasov, A.V., and Hamberg, M. On the mechanism of biosynthesis of divinyl ether oxylipins by enzyme from garlic bulbs Eur. J. Biochem. 245(1),137-142(1997).
2. Hamberg, M. Biosynthesis of new divinyl ether oxylipins in Ranunculus plants Lipids 37(4),427-433(2002).
3. Cowley, T., and Walters, D. Local and systemic effects of oxylipins on powdery mildew infection in barley Pest Manag. Sci. 61(6),572-576(2005).
12-[1-L (E)-hexenyloxy]-9(Z),11(E)-dodecadienoic acid Preparation Products And Raw materials
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