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| | Citronellyl tiglate Basic information |
| Product Name: | Citronellyl tiglate | | Synonyms: | 2-Butenoic acid, 2-methyl-, 3,7-dimethyl-6-octenyl ester, (E)-;2-methyl-,3,7-dimethyl-6-octenylester,(e)-2-butenoicaci;2-methyl-,3,7-dimethyl-6-octenylester,(E)-2-Butenoicacid;3,7-Dimethyl-6-octenyl (2Z)-2-methyl-2-butenoate;E-Citronellyl tiglate;CITRONELLYL TIGLATE;CITRONELLYL-CROTONATE;3,7-dimethyl-6-octenyl 2-methylcrotonate | | CAS: | 24717-85-9 | | MF: | C15H26O2 | | MW: | 238.37 | | EINECS: | 246-426-2 | | Product Categories: | Alphabetical Listings;C-D;Flavors and Fragrances | | Mol File: | 24717-85-9.mol |  |
| | Citronellyl tiglate Chemical Properties |
| Boiling point | 144-145 °C9 mm Hg(lit.) | | density | 0.903 g/mL at 25 °C(lit.) | | vapor pressure | 1.4Pa at 25℃ | | FEMA | 4295 | CITRONELLYL TRANS-2-METHYL-2-BUTENOATE | | refractive index | n20/D 1.465(lit.) | | Fp | >230 °F | | color | A colourless or pale straw-coloured liquid. | | Odor | Fresh-herbaceous, slightly green and warm-rosy odor of moderate tenacity. | | Odor Type | floral | | Water Solubility | 385μg/L at 20℃ | | JECFA Number | 1823 | | Cosmetics Ingredients Functions | PERFUMING | | InChI | 1S/C15H26O2/c1-6-14(5)15(16)17-11-10-13(4)9-7-8-12(2)3/h6,8,13H,7,9-11H2,1-5H3/b14-6+ | | InChIKey | UCFQYMKLDPWFHZ-MKMNVTDBSA-N | | SMILES | O(CCC(CCC=C(C)C)C)C(=O)\C(=C\C)\C | | LogP | 5.99 at 25℃ | | NIST Chemistry Reference | Citronellyl tiglate(24717-85-9) | | EPA Substance Registry System | 2-Butenoic acid, 2-methyl-, 3,7-dimethyl-6-octenyl ester, (2E)- (24717-85-9) |
| WGK Germany | 2 | | TSCA | TSCA listed | | Storage Class | 10 - Combustible liquids | | Hazard Classifications | Aquatic Acute 1
Aquatic Chronic 1
Skin Sens. 1 | | toxicity | Both the acute oral LD50 value in rats and the acute dermal LD50 value in rabbits exceeded 5 g/kg (Moreno, 1975). |
| | Citronellyl tiglate Usage And Synthesis |
| Chemical Properties | Citronellyl Tiglate is a liquid with a floral, rosy, fruity, mushroomlike
odor. It is used in geranium oil reconstitutions. | | Chemical Properties | Colorless liquid; winey rosy aroma. | | Occurrence | Reported found in geranium petiole oil India (3.93%), geranium stem oil India (1.88%), geranium leaf oil
Rwanda (0.14%) and geranium leaf oil India (1.40%). | | Uses | Rarely offered commercially, Citronellyl tiglate has
been suggested for use in floral and herbaceous
fragrances, including better soap perfumes. It has considerable power and good effect in
i
soap, but there are many related chemicals,
some less expensive, others more freely available, with similar effects. | | Preparation | By direct esterification of citronellol with 2-butenoic acid under azeotropic conditions (Arctander. 1969). | | Aroma threshold values | Medium strength odor, floral type. |
| | Citronellyl tiglate Preparation Products And Raw materials |
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