2H-Pyrano[2,3-b]quinoline, 3,4-dihydro-2,5,6,8-tetramethyl-

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2H-Pyrano[2,3-b]quinoline, 3,4-dihydro-2,5,6,8-tetramethyl- Basic information
Product Name:2H-Pyrano[2,3-b]quinoline, 3,4-dihydro-2,5,6,8-tetramethyl-
Synonyms:2H-Pyrano[2,3-b]quinoline, 3,4-dihydro-2,5,6,8-tetramethyl-;2,5,6,8-Tetramethyl-3,4-dihydro-2H-pyrano[2,3-b]quinoline
CAS:1771764-64-7
MF:C16H19NO
MW:241.33
EINECS:
Product Categories:
Mol File:1771764-64-7.mol
2H-Pyrano[2,3-b]quinoline, 3,4-dihydro-2,5,6,8-tetramethyl- Structure
2H-Pyrano[2,3-b]quinoline, 3,4-dihydro-2,5,6,8-tetramethyl- Chemical Properties
Boiling point 404.3±24.0 °C(Predicted)
density 1.079±0.06 g/cm3(Predicted)
form powder
pka5.01±0.40(Predicted)
InChI1S/C16H19NO/c1-9-7-10(2)15-12(4)13-6-5-11(3)18-16(13)17-14(15)8-9/h7-8,11H,5-6H2,1-4H3
InChIKeyLOKRNFHHPZEJLL-UHFFFAOYSA-N
SMILESCC1=C2C(OC(C)CC2)=NC3=C1C(C)=CC(C)=C3
Safety Information
WGK Germany WGK 3
Storage Class11 - Combustible Solids
MSDS Information
2H-Pyrano[2,3-b]quinoline, 3,4-dihydro-2,5,6,8-tetramethyl- Usage And Synthesis
UsesThe Yu Fluorination Ligand in tandem with Selectfluor(R) (Aldrich 439479) under palladium catalysis can promote direct fluorination of C(sp3)-H bonds stereoselectively. Yu and coworkers have displayed this on amino acid derivatives with directing group assistance from the Yu-Wasa Auxiliary (Aldrich 791806).
General DescriptionYu Fluorination Ligand is widely employed for the chemoselective functionalization of sp2- and sp3 C-H bonds.
reaction suitabilityreagent type: catalyst
reagent type: ligand
reaction type: C-H Activation
2H-Pyrano[2,3-b]quinoline, 3,4-dihydro-2,5,6,8-tetramethyl- Preparation Products And Raw materials
Tag:2H-Pyrano[2,3-b]quinoline, 3,4-dihydro-2,5,6,8-tetramethyl-(1771764-64-7) Related Product Information
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