Iododioxobis(triphenylphosphine)rhenium(V)

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Iododioxobis(triphenylphosphine)rhenium(V) Basic information
Uses
Product Name:Iododioxobis(triphenylphosphine)rhenium(V)
Synonyms:Iododioxobis(triphenylphosphine)rhenium(V),98%;Iododioxobis(triphenylphosphine)rhenium;Iododioxobis(triphenylphosphine)rhenium(V)
CAS:23032-93-1
MF:C36H30IO2P2Re
MW:869.68
EINECS:
Product Categories:metal phosphine complex;Catalysis and Inorganic Chemistry;Chemical Synthesis;Rhenium
Mol File:23032-93-1.mol
Iododioxobis(triphenylphosphine)rhenium(V) Structure
Iododioxobis(triphenylphosphine)rhenium(V) Chemical Properties
Melting point 195-197 °C(lit.)
form crystal
color violet
InChI1S/2C18H15P.HI.2O.Re/c2*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;;;;/h2*1-15H;1H;;;/q;;;;;+1/p-1
InChIKeyPMWGPGWRMJAPNT-UHFFFAOYSA-M
SMILESI[Re](=O)=O.c1ccc(cc1)P(c2ccccc2)c3ccccc3.c4ccc(cc4)P(c5ccccc5)c6ccccc6
Safety Information
Risk Statements 20/21/22-36/37/38
Safety Statements 26-36/37/39
WGK Germany 3
Storage Class11 - Combustible Solids
MSDS Information
ProviderLanguage
SigmaAldrich English
Iododioxobis(triphenylphosphine)rhenium(V) Usage And Synthesis
Uses

Iododioxobis(triphenylphosphine)rhenium(V) can be useful catalyst for the ortho-deuteration of anilines, benzylamines, nitrogen heterocycles and functionalized aromatics, in the chemoselective, hydrosilylation of aldehydes and ketones.

UsesCatalyst for:
  • Chemoselective direct reductive amination reactions
  • Selective hydrogenation reactions
  • Living radical polymerization reactions
reaction suitabilitycore: rhenium
reagent type: catalyst
Iododioxobis(triphenylphosphine)rhenium(V) Preparation Products And Raw materials
Tag:Iododioxobis(triphenylphosphine)rhenium(V)(23032-93-1) Related Product Information
Iododioxobis(triphenylphosphine)rhenium(V) Rhenium(IV) oxide Triphenylphosphine hydroiodide RHENIUM Tri(1-naphthyl)phosphine diphenyl-1-pyrenylphosphine