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3-Bromo-4-fluorobenzotrifluoride

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3-Bromo-4-fluorobenzotrifluoride manufacturers

3-Bromo-4-fluorobenzotrifluoride Basic information
Product Name:3-Bromo-4-fluorobenzotrifluoride
Synonyms:2-FLUORO-5-(TRIFLUOROMETHYL)BROMOBENZENE;3-BROMO-4-FLUOROBENZOTRIFLUORIDE;3-BROMO-ALPHA,ALPHA,ALPHA,4-TETRAFLUOROTOLUENE;3-bromo-4-trifluorotoluene;2-Bromo-1-fluoro-4-(trifluoromethyl)benzene~2-Fluoro-5-(trifluoromethyl)bromobenzene;4-fluoro-3-bromobenzoTrifluoride;3-Bromo-4-fluorobenzotrifluori;3-Bromo-4-fluorobenzotrifluoride 97%
CAS:68322-84-9
MF:C7H3BrF4
MW:243
EINECS:
Product Categories:Fluorine series;alkyl bromide| alkyl Fluorine;Halogenated Hydrocarbons;Miscellaneous;Benzotrifluoride Series;Aryl;C7;Fluorobenzene;Trifluoromethylbenzene serise
Mol File:68322-84-9.mol
3-Bromo-4-fluorobenzotrifluoride Structure
3-Bromo-4-fluorobenzotrifluoride Chemical Properties
Boiling point 148-149 °C (lit.)
density 1.706 g/mL at 25 °C (lit.)
refractive index n20/D 1.459(lit.)
Fp 161 °F
storage temp. Sealed in dry,Room Temperature
form clear liquid
Specific Gravity1.710
color Colorless to Light orange to Yellow
BRN 2093911
InChI1S/C7H3BrF4/c8-5-3-4(7(10,11)12)1-2-6(5)9/h1-3H
InChIKeyRZJOIMPUMMQKFR-UHFFFAOYSA-N
SMILESFc1ccc(cc1Br)C(F)(F)F
CAS DataBase Reference68322-84-9(CAS DataBase Reference)
NIST Chemistry Reference3-Bromo-4-fluorobenzotrifluoride(68322-84-9)
Safety Information
Hazard Codes C,Xi,Xn
Risk Statements 34-36/37/38-20/21/22
Safety Statements 45-36/37/39-26-36/37-36-24/25
RIDADR UN1760
WGK Germany 3
HazardClass IRRITANT
HS Code 29039990
Storage Class10 - Combustible liquids
MSDS Information
ProviderLanguage
SigmaAldrich English
ACROS English
ALFA English
3-Bromo-4-fluorobenzotrifluoride Usage And Synthesis
Chemical Propertiesclear colorless liquid
Uses3-Bromo-4-fluorobenzotrifluoride is used as a pharmaceutical and pesticide intermediate.
SynthesisIn a 2000ml three-necked flask, 400g of concentrated sulfuric acid,p-fluorobenzotrifluoride 400g, lithium bromide 10g, ferric bromide 20g, tetrabutylammonium bromide 10g, Bromine 234.14g, temperature control 35-45 ° C, the reaction 6h, GC detection of raw materials 0.36percent. Cooled to below 30, transferred to 2000ml separation funnel, stationary 1h, the acid was separated, the crude product was placed in 2000 ml bottle,1000g of water was added under stirring, dropping 10 percent sodium hydroxide solution to adjust PH = 7,548.6 g of 3-bromo-4-fluorobenzotrifluoride was isolated at a constant rate of 92.56percent with 97.9 percent.
References[1] Patent: CN105152853, 2017, B. Location in patent: Paragraph 0030
3-Bromo-4-fluorobenzotrifluoride Preparation Products And Raw materials
Raw materials4-Fluorobenzotrifluoride
Preparation ProductsBenzene, 1-fluoro-4-(trifluoromethyl)-2-[2-(trimethylsilyl)ethynyl]-
Tag:3-Bromo-4-fluorobenzotrifluoride(68322-84-9) Related Product Information
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