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ARSENIC (III) BROMIDE

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ARSENIC (III) BROMIDE Basic information
Product Name:ARSENIC (III) BROMIDE
Synonyms:tribromoarsane;ARSENIC (OUS) BROMIDE;ARSENIC TRIBROMIDE;Arsenic(iii) bromide, 99.90%;Arsenic(III) tribromide;Arsenic(III) bromide,99.99%;ARSENIC (III) BROMIDE;Arsenic(ii) bromide
CAS:7784-33-0
MF:AsBr3
MW:314.63
EINECS:232-057-4
Product Categories:metal halide
Mol File:7784-33-0.mol
ARSENIC (III) BROMIDE Structure
ARSENIC (III) BROMIDE Chemical Properties
Melting point 31 °C
Boiling point 221 °C
density 3,54 g/cm3
solubility reacts with H2O; soluble in hydrocarbon solvents, ctc;very soluble in ethyl ether, benzene
form yellow orthorhombic crystals
Specific Gravity3.54
color Colorless, deliquescent, rhombic crystals
Water Solubility decomposed in H2O, forming HBr, As2O3; miscible with ether, benzene [MER06]
Specific Heat CapacityCp(gas): 0.25 J/(g·K), at 25℃
Sensitive moisture sensitive
Dielectric constant9.0(37℃)
EPA Substance Registry SystemArsenous tribromide (7784-33-0)
Safety Information
Hazard Codes N-T,N,T
Risk Statements 50/53-45-34-23/25
Safety Statements 61-60-53-36/37/39-28A-20/21-45-28
RIDADR UN 1555
TSCA TSCA listed
HazardClass 6.1
PackingGroup II
Hazardous Substances Data7784-33-0(Hazardous Substances Data)
MSDS Information
ProviderLanguage
ACROS English
ARSENIC (III) BROMIDE Usage And Synthesis
Chemical PropertiesFaintly yellow solid
UsesAnalytical chemistry, medicine.
Safety ProfileConfirmed human carcinogen. A poison. See also ARSENIC COMPOUNDS and BROMIDES. When heated to decomposition it emits very toxic fumes of As and Br-.
SynthesisA boat is placed in a Pyrex tube and filled with As powder. A stream of dry N3, saturated with Br 3 vapor by passage through a Br2-filled wash bottle, is passed over the As. The tube is inclined toward the receiver and connected with the latter by means of an asbestos-paper-sealed adapter. The tube is heated until the onset of reaction. The product is distilled from the receiver over As powder.
Purification MethodsIt hydrolyses in H2O, but less readily than AsCl3. POISONOUS. [Schenk in Handbook of Preparative Inorganic Chemistry (Ed. Brauer) Academic Press Vol I p 597 1963.]
Tag:ARSENIC (III) BROMIDE(7784-33-0) Related Product Information
Triphenylarsine Tetraphenylarsonium chloride Cacodylic acid Tris(dimethylamino)arsine Triethylarsine Trimethylarsine Arsenic pentoxide Phenylarsonic acid Cadmium selenide ARSENIC (III) SELENIDE Beryllium Arsenic(III) oxide ARSENIC(III) IODIDE ARSENIC (III) SULFIDE ARSENIC(III) CHLORIDE Arsenic ARSENIC (III) BROMIDE ARSINE