N-Ethoxycarbonylmethyl-oxalamic acid ethyl ester

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Products Intro: Product Name:ethyl 2-((2-ethoxy-2-oxoethyl)amino)-2-oxoacetate
CAS:29655-79-6
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Products Intro: Product Name:Ethyl 2-((2-ethoxy-2-oxoethyl)amino)-2-oxoacetate
CAS:29655-79-6
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Products Intro: Product Name:N-Ethoxycarbonylmethyl-oxalamic acid ethyl ester
CAS:29655-79-6
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Products Intro: Product Name:Ethyl 2-((2-ethoxy-2-oxoethyl)amino)-2-oxoacetate
CAS:29655-79-6
Purity:98% Min. Package:5KG;1KG
N-Ethoxycarbonylmethyl-oxalamic acid ethyl ester Basic information
Product Name:N-Ethoxycarbonylmethyl-oxalamic acid ethyl ester
Synonyms:N-Ethoxycarbonylmethyl-oxalamic acid ethyl ester;N-EthoxycarboMylMethyl-oxalaMic acid ethyl ester;(CarboxyMethyl)oxaMic Acid Diethyl Ester;N-(2-Ethoxy-2-oxoacetyl)glycine ethyl ester;Glycine, N-(2-ethoxy-2-oxoacetyl)-, ethyl ester;Ethyl 2-((2-ethoxy-2-oxoethyl);2-[(2-ethoxy-2-oxoethyl)amino]-2-oxoacetic acid ethyl ester
CAS:29655-79-6
MF:C8H13NO5
MW:203.19
EINECS:
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Mol File:29655-79-6.mol
N-Ethoxycarbonylmethyl-oxalamic acid ethyl ester Structure
N-Ethoxycarbonylmethyl-oxalamic acid ethyl ester Chemical Properties
storage temp. Sealed in dry,Room Temperature
Cosmetics Ingredients FunctionsHAIR CONDITIONING
Safety Information
HS Code 29420000
MSDS Information
N-Ethoxycarbonylmethyl-oxalamic acid ethyl ester Usage And Synthesis
Uses(Carboxymethyl)oxamic Acid Diethyl Ester, is an intermediate in various chemical synthesis. It is used in the preparation of 5-alkoxyoxazoles, used in Diels-Alder process.
Synthesis
Glycine ethyl ester hydrochloride

623-33-6

Ethyl chlorooxoacetate

4755-77-5

N-Ethoxycarbonylmethyl-oxalamic acid ethyl ester

29655-79-6

Example 2 II: Compound 4 was prepared using ethyl glycinate hydrochloride and ethyl oxalyl chloride monoethyl ester as starting materials with reference to the literature (J. Heterocycl. Chem. 1995, 32, 1693-1702).Subsequently, the reduction reaction was carried out using the NaBH4/LiCl system in ethanol solution. Further oxidation by Dess-Martin oxidizer gave the target aldehyde 6 in 25% overall yield (two-step reaction).

References[1] Synthetic Communications, 2000, vol. 30, # 17, p. 3171 - 3180
[2] Patent: WO2007/124546, 2007, A1. Location in patent: Page/Page column 63
[3] Chemische Berichte, 1897, vol. 30, p. 590
[4] Journal of the American Chemical Society, 1997, vol. 119, # 1, p. 86 - 93
[5] Organic Process Research and Development, 2004, vol. 8, # 2, p. 192 - 200
N-Ethoxycarbonylmethyl-oxalamic acid ethyl ester Preparation Products And Raw materials
Raw materialsEthyl chlorooxoacetate-->Ethyl glyoxalate-->Dichloromethane-->Triethylamine-->Glycine ethyl ester hydrochloride
Preparation Products5-Ethoxy-2-oxazolecarboxylic Acid
Tag:N-Ethoxycarbonylmethyl-oxalamic acid ethyl ester(29655-79-6) Related Product Information
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