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| | Cyclopentylzinc bromide Basic information |
| Product Name: | Cyclopentylzinc bromide | | Synonyms: | cyclopentylzinc bromide solution;CYCLOPENTYLZINC BROMIDE, 0.5M SOLUTION I N TETRAHYDROFURAN;Cyclopentylzinc bromide solution 0.5 in THF;Cyclopentylzinc broMide, 0.5M in THF, packaged under Argon in resealable CheMSeal^t bottles;cyclopentylzinc(II) broMide;Cyclopentylzinc broMide solution 0.5 M in THF;Cyclopentylzinc broMide, 0.5 M solution in THF, SpcSeal;Zinc, bromocyclopentyl- | | CAS: | 171860-68-7 | | MF: | C5H9BrZn | | MW: | 214.42 | | EINECS: | | | Product Categories: | Alkyl;Organozinc Halides;Reike and Organozinc Reagents | | Mol File: | 171860-68-7.mol |  |
| | Cyclopentylzinc bromide Chemical Properties |
| density | 0.955 g/mL at 25 °C | | Fp | 1 °F | | storage temp. | 2-8°C | | Water Solubility | Reacts with water. | | Sensitive | Air Sensitive | | InChI | 1S/C5H9.BrH.Zn/c1-2-4-5-3-1;;/h1H,2-5H2;1H;/q;;+1/p-1 | | InChIKey | GOPYCBPMCCJYSN-UHFFFAOYSA-M | | SMILES | Br[Zn]C1CCCC1 |
| Hazard Codes | F,Xn | | Risk Statements | 11-14-19-22-36/37/38-40-36/37 | | Safety Statements | 16-26-33-36-36/37 | | RIDADR | UN 3399 4.3/PG 2 | | WGK Germany | 1 | | HazardClass | 4.3 | | HS Code | 29319090 | | Storage Class | 4.3 - Hazardous materials which set free flammable gases upon contact with water | | Hazard Classifications | Acute Tox. 4 Oral
Carc. 2
Eye Irrit. 2
Flam. Liq. 2
Skin Irrit. 2
STOT SE 3
Water-react 2 |
| | Cyclopentylzinc bromide Usage And Synthesis |
| Uses | Cyclopentylzinc bromide is an organozinc reagent that can be used in:
- The synthesis of polyfunctional indoles by reacting with various aryldiazonium salts via Fischer indole synthesis.
- Negishi cross-coupling reactions with various haloarenes in presence of Pd-complex catalyst.
- The preparation of aryl alkyl ketones by alkylation of aryl N-methyl-N-tosyl or N-benzyl-N-(tert-butoxycarbonyl) amide derivatives in the presence of Ni catalyst and imidazolidinylidene ligand.
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| | Cyclopentylzinc bromide Preparation Products And Raw materials |
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