cis-Dichlorobis(triphenylphosphine)platinum(II)

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cis-Dichlorobis(triphenylphosphine)platinum(II) Basic information
Product Name:cis-Dichlorobis(triphenylphosphine)platinum(II)
Synonyms:TRANS-DICHLOROBIS(TRIPHENYLPHOSPHINE)PLATINUM(II);trans-Bis(triphenylphosphine)platinum dichloride;DICHLOROBIS(TRIPHENYLPHOSPHINE)PLATINATE (II);CIS PTCL2(PPH3)2;CIS-BIS(TRIPHENYLPHOSPHINE)PLATINUM(II) DICHLORIDE;Chlorotri platinuM;trans-Dichlorobis(triphenylphosphine)platinum(II)
CAS:14056-88-3
MF:C36H30Cl2P2Pt
MW:790.55
EINECS:
Product Categories:Catalysis and Inorganic Chemistry;Chemical Synthesis;Platinum
Mol File:14056-88-3.mol
cis-Dichlorobis(triphenylphosphine)platinum(II) Structure
cis-Dichlorobis(triphenylphosphine)platinum(II) Chemical Properties
Melting point ≥300 °C(lit.)
storage temp. under inert gas (nitrogen or Argon) at 2–8 °C
InChI1S/2C18H15P.2ClH.Pt/c2*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;;;/h2*1-15H;2*1H;/q;;;;+2/p-2
InChIKeyXAFJSPPHVXDRIE-UHFFFAOYSA-L
SMILESCl[Pt]Cl.c1ccc(cc1)P(c2ccccc2)c3ccccc3.c4ccc(cc4)P(c5ccccc5)c6ccccc6
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38
Safety Statements 26-37/39
WGK Germany 3
Storage Class11 - Combustible Solids
Hazard ClassificationsAcute Tox. 4 Oral
Eye Irrit. 2
Resp. Sens. 1
Skin Irrit. 2
Skin Sens. 1
STOT RE 2
STOT SE 3
MSDS Information
ProviderLanguage
SigmaAldrich English
ALFA English
cis-Dichlorobis(triphenylphosphine)platinum(II) Usage And Synthesis
UsesCatalyst for:
  • Preparation of soluble polymers of monosubstituted acetylenes with quaternary ammonium pendant groups
  • Alkynylation and hydrogenation reactions
  • Hetero-Diels-Alder/ring-opening reactions
  • Insertion of carbenes into O-H bonds of alcohols
  • Cyclopropanation of olefins
  • Hydroformylation reactions
reaction suitabilitycore: platinum
reagent type: catalyst
cis-Dichlorobis(triphenylphosphine)platinum(II) Preparation Products And Raw materials
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