2,4,6-三嘧啶基三嗪
| 中文名称 | 2,4,6-三嘧啶基三嗪 |
|---|---|
| 中文同义词 | 2,4,6-三嘧啶基三嗪;2,4,6-三(2-嘧啶基)-1,3,5-三嗪;2,4,6-三(嘧啶-2-基)-1,3,5-三嗪 |
| 英文名称 | Tris-2,4,6-(2-pyrimidyl)-1,3,5-triazine |
| 英文同义词 | 1,3,5-TRIAZINE, 2,4,6-TRI-2-PYRIMIDINYL-;Tris-2,4,6-(2-pyrimidyl)-1,3,5-triazine;2,4,6-tri(pyrimidin-2-yl)-1,3,5-triazine;2,4,6-tris(2-pyrimidyl)-1,3,5-triazine |
| CAS号 | 60681-68-7 |
| 分子式 | C15H9N9 |
| 分子量 | 315.29 |
| EINECS号 | |
| 相关类别 | |
| Mol文件 | 60681-68-7.mol |
| 结构式 |  |
2,4,6-三嘧啶基三嗪 性质
| 熔点 | 450-455 °C(Solv: water (7732-18-5)) |
|---|---|
| 沸点 | 740.4±43.0 °C(Predicted) |
| 密度 | 1.405±0.06 g/cm3(Predicted) |
| 酸度系数(pKa) | -0.42±0.33(Predicted) |
可作为配体用于合成MOF材料，如：[Co(bpcam)2]ClO4·dmso·H2O;[Cd2(TPymT)(SO4)2(H2O)6];[Ag2(BPymTz)2]
[2] 2,4,6-Tris(2-pyrimidyl)- and 2,4,6-tris(2-pyridyl)-1,3,5-triazines hydrolyze in the presence of copper(II) to form a novel bis(aryl)carboximidato chelate complex. https://doi.org/10.1021/ja00433a061
[3] Self-assembly of multicomponent multimetallic lead(II) complexes of cylindrical architecture. https://doi.org/10.1002/(SICI)1521-3765(19990401)5:4<1234::AID-CHEM1234>3.0.CO;2-G
[4] From discrete molecule, to polymer, to MOF: mapping the coordination chemistry of CdII using 113Cd solid-state NMR. https://doi.org/10.1039/C6CC04940K
[5] Anion-induced AgI self-assemblies with electron deficient aromatic ligands: anion-π-system interactions as a driving force for templated coordination networks. https://doi.org/10.1039/C5CC01597A
参考文献
[1] The synthesis of certain substituted 1,3,5-triazines containing the ferroin group. https://doi.org/10.1021/ja01513a037
[2] 2,4,6-Tris(2-pyrimidyl)- and 2,4,6-tris(2-pyridyl)-1,3,5-triazines hydrolyze in the presence of copper(II) to form a novel bis(aryl)carboximidato chelate complex. https://doi.org/10.1021/ja00433a061
[3] Self-assembly of multicomponent multimetallic lead(II) complexes of cylindrical architecture. https://doi.org/10.1002/(SICI)1521-3765(19990401)5:4<1234::AID-CHEM1234>3.0.CO;2-G
[4] From discrete molecule, to polymer, to MOF: mapping the coordination chemistry of CdII using 113Cd solid-state NMR. https://doi.org/10.1039/C6CC04940K
[5] Anion-induced AgI self-assemblies with electron deficient aromatic ligands: anion-π-system interactions as a driving force for templated coordination networks. https://doi.org/10.1039/C5CC01597A