(2S,2'S)-2,2'-(1,3,6,8-tetraoxobenzo[lmn][3,8]phenanthroline-2,7(1H,3H,6H,8H)-diyl)dipropanoic acid
| 中文名称 | (2S,2'S)-2,2'-(1,3,6,8-tetraoxobenzo[lmn][3,8]phenanthroline-2,7(1H,3H,6H,8H)-diyl)dipropanoic acid |
|---|---|
| 中文同义词 | N,N'-二(L-丙氨酸基)萘二酰亚胺;(2S,2'S)-2,2'-(1,3,6,8-四氧代-1,3,6,8-四氢苯并[LMN][3,8]菲咯啉-2,7-二基)二丙酸;(2S,2'S)-2,2'-(1,3,6,8-四氧代苯并[LMN][3,8]菲咯啉-2,7(1H,3H,6H,8H)-二基)二丙酸;(2S,2'S)-2,2'-(1,3,6,8-TETRAOXOBENZO[LMN][3,8]PHENANTHROLINE-2,7(1H,3H,6H,8H)-DIYL)DIPROPANOIC ACID |
| 英文名称 | (2S,2'S)-2,2'-(1,3,6,8-tetraoxobenzo[lmn][3,8]phenanthroline-2,7(1H,3H,6H,8H)-diyl)dipropanoic acid |
| 英文同义词 | (2S,2'S)-2,2'-(1,3,6,8-tetraoxobenzo[lmn][3,8]phenanthroline-2,7(1H,3H,6H,8H)-diyl)dipropanoic acid;Benzo[lmn][3,8]phenanthroline-2,7-diacetic acid, 1,3,6,8-tetrahydro-α2,α7-dimethyl-1,3,6,8-tetraoxo-, (α2S,α7S)-;(2S,2'S)-2,2'-(1,3,6,8-Tetraoxo-1,3,6,8-tetrahydrobenzo[lmn][3,8]phenanthroline-2,7-diyl)dipropionic acid;H2AlaNDI;(S)-2-(7-((R)-1-carboxyethyl)-1,3,6,8-tetraoxo-3,6,7,8-tetrahydrobenzo[lmn][3,8]phenanthrolin-2(1H)-yl)propanoic acid |
| CAS号 | 429692-85-3 |
| 分子式 | C20H14N2O8 |
| 分子量 | 410.33 |
| EINECS号 | |
| 相关类别 | 科研材料中间体 |
| Mol文件 | 429692-85-3.mol |
| 结构式 | ![(2S,2'S)-2,2'-(1,3,6,8-tetraoxobenzo[lmn][3,8]phenanthroline-2,7(1H,3H,6H,8H)-diyl)dipropanoic acid 结构式](CAS/20210111/GIF/429692-85-3.gif) |
(2S,2'S)-2,2'-(1,3,6,8-tetraoxobenzo[lmn][3,8]phenanthroline-2,7(1H,3H,6H,8H)-diyl)dipropanoic acid 性质
| 熔点 | 324-326 °C (decomp)(Solv: water (7732-18-5)) |
|---|---|
| 沸点 | 745.4±55.0 °C(Predicted) |
| 密度 | 1.686±0.06 g/cm3(Predicted) |
| 酸度系数(pKa) | 3.18±0.10(Predicted) |
(2S,2'S)-2,2'-(1,3,6,8-tetraoxobenzo[lmn][3,8]phenanthroline-2,7(1H,3H,6H,8H)-diyl)dipropanoic acid 用途与合成方法
可作为配体用于合成MOF材料：IPMOP;AlaNDI-Cd
[2] Inclined 1D→2D polycatenation of chiral chains with large π-surfaces. https://doi.org/10.1039/c3ce41538d
[3] Hydrophobic Shielding of Outer Surface: Enhancing the Chemical Stability of Metal–Organic Polyhedra. https://doi.org/10.1002/anie.201811037
[4] Heterochiral Doped Supramolecular Coordination Networks for High-Performance Optoelectronics. https://doi.org/10.1021/acsami.9b04653
参考文献
[1] Cyclomaltooligosaccharide (cyclodextrin)-assisted enantiomeric recognition of benzo[lmn][3,8]phenanthroline-derived amino acids. https://doi.org/10.1016/j.carres.2005.03.002
[2] Inclined 1D→2D polycatenation of chiral chains with large π-surfaces. https://doi.org/10.1039/c3ce41538d
[3] Hydrophobic Shielding of Outer Surface: Enhancing the Chemical Stability of Metal–Organic Polyhedra. https://doi.org/10.1002/anie.201811037
[4] Heterochiral Doped Supramolecular Coordination Networks for High-Performance Optoelectronics. https://doi.org/10.1021/acsami.9b04653