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| | POTASSIUM DIPHENYLPHOSPHIDE Basic information |
| Product Name: | POTASSIUM DIPHENYLPHOSPHIDE | | Synonyms: | Potassium diphenylphosphide solution,Diphenylphosphine potassium salt;Potassium diphenylphosphide solution 0.5 in THF;DIPHENYLPHOSPHINE POTASSIUM SALT;KPPh2;Potassium diphenylphosphine;potassium diphenylphosphide solution;POTASSIUM DIPHENYLPHOSPHIDE SOLUTION, ~0 .5 M IN THF;POTASSIUM DIPHENYLPHOSPHIDE, 0.5M SOLUTI | | CAS: | 15475-27-1 | | MF: | C12H12KP | | MW: | 226.3 | | EINECS: | | | Product Categories: | | | Mol File: | 15475-27-1.mol |  |
| | POTASSIUM DIPHENYLPHOSPHIDE Chemical Properties |
| density | 0.929 g/mL at 25 °C | | Fp | −4 °F | | form | liquid | | BRN | 4164304 | | InChI | 1S/C12H10P.K/c1-3-7-11(8-4-1)13-12-9-5-2-6-10-12;/h1-10H;/q-1;+1 | | InChIKey | FCLYZQXPJKJTDR-UHFFFAOYSA-N | | SMILES | [K]P(c1ccccc1)c2ccccc2 |
| Hazard Codes | F,C | | Risk Statements | 11-19-22-34-40-37 | | Safety Statements | 16-26-33-36/37/39-45 | | RIDADR | UN 2924 3/PG 2 | | WGK Germany | 1 | | F | 1-8-10-13 | | Storage Class | 3 - Flammable liquids | | Hazard Classifications | Acute Tox. 4 Oral
Carc. 2
Flam. Liq. 2
Skin Corr. 1B
STOT SE 3 |
| | POTASSIUM DIPHENYLPHOSPHIDE Usage And Synthesis |
| Uses |
- Synthesis, reactivity and molecular structure of phosphino tetramethyl cyclopentadienyl complex (eta5: eta1-C5Me4CH2PPh2)Re(CO)2.: This study explores the synthesis and reactivity of a novel phosphino complex, utilizing Potassium diphenylphosphide as a key reagent. The research highlights the molecular structure and potential applications in organometallic chemistry (Godoy et al., 2009).
- Improved and efficient synthesis of chiral N,P-ligands via cyclic sulfamidates for asymmetric addition of butyllithium to benzaldehyde.: This paper details an improved synthesis method for chiral N,P-ligands using Potassium diphenylphosphide. The research demonstrates the compound′s efficacy in asymmetric synthesis, offering potential advancements in drug discovery and development (Rönnholm et al., 2007).
- Coordination chemistry of diselenophosphinate complexes: the X-ray single-crystal structures of [K(Se2PPh2)(THF)2]2 and [In(Se2PPh2)3].L (L = THF, PhMe).: This article investigates the coordination chemistry involving diselenophosphinate complexes, with Potassium diphenylphosphide playing a crucial role. The study provides detailed X-ray crystallographic data, offering insights for future research in chemical synthesis and materials science (Davies et al., 2004).
| | reaction suitability | reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: ligand |
| | POTASSIUM DIPHENYLPHOSPHIDE Preparation Products And Raw materials |
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