2-(4-Pyridil)-5,5-dimethyl-1,3,2-dioxaboronane

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2-(4-Pyridil)-5,5-dimethyl-1,3,2-dioxaboronane Basic information
Product Name:2-(4-Pyridil)-5,5-dimethyl-1,3,2-dioxaboronane
Synonyms:2-(4-PYRIDYL)-5,5-DIMETHYL-1,2,3-DIOXABORINANE;2-(3-PYRIDYL)-5,5-DIMETHYL-1,2,3-DIOXABORANE;2-(3-PYRIDYL)-5,5-DIMETHYL-1,3,2-DIOXABORINANE;2-(3-PYRIDIL)-5,5-DIMETHYL-1,3,2-DIOXABORONANE;5,5-Dimethyl-2-(3-pyridyl)-1,3,2-dioxaborinane, Pyridine-3-boronic acid neopentylglycol ester;PYRIDINE-3-BORONIC ACID, NEOPENTYL ESTER;PYRIDINE-3-BORONIC ACID NEOPENTYLGLYCOL ESTER;5,5-Dimethyl-2-(pyridin-3-yl)-1,3,2-dioxaborinane
CAS:845885-86-1
MF:C10H14BNO2
MW:191.03
EINECS:
Product Categories:
Mol File:845885-86-1.mol
2-(4-Pyridil)-5,5-dimethyl-1,3,2-dioxaboronane Structure
2-(4-Pyridil)-5,5-dimethyl-1,3,2-dioxaboronane Chemical Properties
Melting point 92-96 °C (lit.)
Boiling point 309.8±15.0 °C(Predicted)
density 1.05±0.1 g/cm3(Predicted)
storage temp. under inert gas (nitrogen or Argon) at 2-8°C
form solid
pka5.22±0.12(Predicted)
color white
InChI1S/C10H14BNO2/c1-10(2)7-13-11(14-8-10)9-4-3-5-12-6-9/h3-6H,7-8H2,1-2H3
InChIKeyQMEKTOQBDDVVBE-UHFFFAOYSA-N
SMILESCC1(C)COB(OC1)c2cccnc2
CAS DataBase Reference845885-86-1(CAS DataBase Reference)
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38
Safety Statements 26-36
WGK Germany 3
HazardClass IRRITANT
HS Code 2933399990
Storage Class11 - Combustible Solids
Hazard ClassificationsEye Irrit. 2
Skin Irrit. 2
STOT SE 3
MSDS Information
ProviderLanguage
SigmaAldrich English
2-(4-Pyridil)-5,5-dimethyl-1,3,2-dioxaboronane Usage And Synthesis
Uses3-Pyridineboronic acid neopentylglycol ester can be used as a reactant:
  • To synthesize N-alkyl-3-boronopyridinium salts by reacting with corresponding alkyl halides.
  • In the ruthenium-catalyzed diastereoselective C-H bond α-arylation of cyclic amines.
  • To prepare 2-(3-pyridyl)benzoxazole by reacting with benzoxazole via copper-catalyzed oxidative arylation reaction.
  • In the Suzuki-Miyaura cross-coupling reaction.

2-(4-Pyridil)-5,5-dimethyl-1,3,2-dioxaboronane Preparation Products And Raw materials
Tag:2-(4-Pyridil)-5,5-dimethyl-1,3,2-dioxaboronane(845885-86-1) Related Product Information
Isoquinoline-4-boronic acid 2,2-dimethylpropanediol-1,3 cyclic ester 5-(5,5-Dimethyl-1,3,2-dioxaborinan-2-yl)-2-methoxypyridine 3-Chloro-4-(5, 5-dimethyl-1,3,2-dioxaborinan-2-yl)pyridine 2-(4-Pyridil)-5,5-dimethyl-1,3,2-dioxaboronane 4-Cyanopyridine-3-boronic acid neopentyl glycol ester 3-Cyano-4-(5,5-Dimethyl-[1,3,2]Dioxaborinan-2-Yl)-Pyridine 2-Cyanopyridine-3-boronic acid neopentyl glycol ester 3-(5,5-Dimethyl-1,3,2-dioxaborinan-2-yl)-4-fluoropyridine 2,6-Dichloro-3-(5,5-dimethyl-1,3,2-dioxaborinan-2-yl)pyridine 3-(5,5-Dimethyl-1,3,2-dioxaborinan-2-yl)-2,6-difluoropyridine 3-(5,5-Dimethyl-1,3,2-dioxaborinan-2-yl)quinoline 4-(5,5-Dimethyl-1,3,2-dioxaborinan-2-yl)-3-fluoropyridine 5-(5,5-Dimethyl-1,3,2-dioxaborinan-2-yl)-nicotinic acid 2,3-Dichloro-4-(5,5-dimethyl-1,3,2-dioxaborinan-2-yl)pyridine 4-Chloro-3-(5,5-dimethyl-1,3,2-dioxaborinan-2-yl)pyridine 5-Bromo-2-chloro-3-(5,5-dimethyl-1,3,2-dioxaborinan-2-yl)pyridine