Diethyl phenylthiomethylphosphonate

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Diethyl phenylthiomethylphosphonate Basic information
Product Name:Diethyl phenylthiomethylphosphonate
Synonyms:Diethyl (phenylsulfanyl)methylphosphonate;Diethyl methylthiobenzyl phosphonate;Phosphonic acid, [(phenylthio)methyl]-, diethyl ester;LABOTEST-BB LT00453966;Diethyl phenylthiomethanephosphonate;NSC 202497;Diethyl[(phenylthio)methyl]phosphonate, 97 %;Phosphonic acid, P-[(phenylthio)methyl]-, diethyl ester
CAS:38066-16-9
MF:C11H17O3PS
MW:260.29
EINECS:253-770-7
Product Categories:
Mol File:38066-16-9.mol
Diethyl phenylthiomethylphosphonate Structure
Diethyl phenylthiomethylphosphonate Chemical Properties
Boiling point 146-148 °C (0.5 mmHg)
density 1.17
refractive index 1.53-1.533
Fp 146-148°C/0.5mm
solubility Difficult to mix.
form Liquid
Specific Gravity1.174
BRN 1246215
CAS DataBase Reference38066-16-9(CAS DataBase Reference)
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38
Safety Statements 37/39-26
HS Code 2931499090
MSDS Information
ProviderLanguage
ACROS English
ALFA English
Diethyl phenylthiomethylphosphonate Usage And Synthesis
Chemical Propertiesclear light yellow liquid
UsesDiethyl phenylthiomethylphosphonate is used to produce Diethylphosphorylmethylphenylsulfoxid, Chemical reagents, pharmaceutical research, pharmaceutical intermediates.
ApplicationDiethyl phenylthiomethylphosphonate used for the conversion of aldehydes and ketones to vinyl sulfides, which can be hydrolyzed to yield  homologated aldehydes and ketones.
PreparationThe Arbuzov reaction between phenylthiomethyl chloride (Chloromethyl Phenyl Sulfide) and Triethyl  Phosphite is the most commonly used method of preparation (eq 1).
DIETHYL PHENYLTHIOMETHYLPHOSPHONATE
Synthesis Reference(s)Synthesis, p. 309, 1978 DOI: 10.1055/s-1978-24736
Diethyl phenylthiomethylphosphonate Preparation Products And Raw materials
Tag:Diethyl phenylthiomethylphosphonate(38066-16-9) Related Product Information
Diethyl fluoro(phenylsulfonyl)methylphosphonate Diethyl (phenylsulfonyl)methanephosphonate Bis[(4-chlorophenyl)thiomethylene]biphosphonic acid, tetraisopropyl ester Diethyl phenylthiomethylphosphonate Diethyl methylphosphonate AURORA KA-1460