(2-Aminobenzyl)triphenylphosphonium bromide

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(2-Aminobenzyl)triphenylphosphonium bromide Basic information
Product Name:(2-Aminobenzyl)triphenylphosphonium bromide
Synonyms:(2-Aminobenzyl)triphenylphosphonium bromide 97%;(2-aminophenyl)methyl-triphenylphosphanium;(2-aminophenyl)methyl]triphenylphosphanium bromide;(2-Aminobenzyl)triphenylphosphonium bromide
CAS:78133-84-3
MF:C25H23BrNP
MW:448.33
EINECS:
Product Categories:C-C Bond Formation;Olefination;Wittig Reagents
Mol File:78133-84-3.mol
(2-Aminobenzyl)triphenylphosphonium bromide Structure
(2-Aminobenzyl)triphenylphosphonium bromide Chemical Properties
Melting point 245 °C (dec.)(lit.)
InChI1S/C25H23NP.BrH/c26-25-19-11-10-12-21(25)20-27(22-13-4-1-5-14-22,23-15-6-2-7-16-23)24-17-8-3-9-18-24;/h1-19H,20,26H2;1H/q+1;/p-1
InChIKeyFBTZMAUPYYNVPM-UHFFFAOYSA-M
SMILES[Br-].Nc1ccccc1C[P+](c2ccccc2)(c3ccccc3)c4ccccc4
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38
Safety Statements 26-36
WGK Germany 3
Storage Class11 - Combustible Solids
Hazard ClassificationsEye Irrit. 2
Skin Irrit. 2
STOT SE 3
MSDS Information
ProviderLanguage
SigmaAldrich English
(2-Aminobenzyl)triphenylphosphonium bromide Usage And Synthesis
UsesReactant for:
  • Intramolecular Wittig reaction
  • Preparation of 2,3-disubstituted indoles
  • Preparation of pyrrolocarbazoles as poly(ADP-ribose) polymerase-1 (PARP-1) inhibitors
reaction suitabilityreaction type: C-C Bond Formation
(2-Aminobenzyl)triphenylphosphonium bromide Preparation Products And Raw materials
Tag:(2-Aminobenzyl)triphenylphosphonium bromide(78133-84-3) Related Product Information
(2-Aminobenzyl)triphenylphosphonium bromide (2-Nitrobenzyl)triphenylphosphonium bromide monohydrate Benzyltriphenylphosphonium bromide Tri(o-tolyl)phosphine Diphenyl(2,4,6-trimethylbenzoyl)phosphine oxide Benzyltriphenylphosphonium chloride