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Lanthanum oxide

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Lanthanum oxide Chemical Properties
Melting point 2315 °C
Boiling point 4200 °C
bulk density1300kg/m3
density 6.51 g/mL at 25 °C(lit.)
Fp 4200°C
storage temp. no restrictions.
solubility insoluble in H2O; soluble in dilute acid solutions
form nanopowder
color White to yellow
Specific Gravity6.51
PH9.0 (50g/l, H2O, 20℃)(slurry)
Resistivity1 ∞ 10*14 (550°C) (ρ/μΩ.cm)
Water Solubility INSOLUBLE
Sensitive Hygroscopic
Crystal StructureTrigonal
crystal systemThree sides
Merck 14,5363
Space groupP3m1
Lattice constant
a/nmb/nmc/nmα/oβ/oγ/oV/nm3
0.3940.3940.61390901200.0824
Stability:Stable.
Major Applicationbattery manufacturing
InChI1S/2La.3O
InChIKeyKTUFCUMIWABKDW-UHFFFAOYSA-N
SMILESO=[La]O[La]=O
LogP1 at 20℃
CAS DataBase Reference1312-81-8(CAS DataBase Reference)
EPA Substance Registry SystemLanthanum oxide (La2O3) (1312-81-8)
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38-36
Safety Statements 26-36-39
WGK Germany 1
RTECS OE5330000
TSCA TSCA listed
HS Code 28469000
Storage Class13 - Non Combustible Solids
ToxicityLD50 orally in Rabbit: > 9968 mg/kg
MSDS Information
ProviderLanguage
Lanthanum(III) oxide English
SigmaAldrich English
ACROS English
ALFA English
Lanthanum oxide Usage And Synthesis
Chemical PropertiesLanthanum oxide is an oxide of lanthanum (III), white orthorhombic or amorphous powder. Soluble in acid, ethanol, ammonium chloride, insoluble in water, ketone. It is mainly used in the manufacture of precision optical glass and optical fiber.
UsesLanthanum oxide is used to make high-quality glass, ceramics, carbon-arc electrodes, and fluorescent lamps. Lanthanum (III) oxide was used as an analytical standard in inductively coupled plasma atomic emission spectrometry (ICP-AES) for chemical characterization of ancient pottery.
UsesLanthanum(III) oxide is used as a precursor to LAMOX fast ion conductors and superconductors. It is also used in the manufacture of optical glasses, piezoelectric and thermoelectric material. It is also useful for X-ray imaging intensifying screens, phosphors as well as dielectric and conductive ceramics. In addition, it is used as a catalyst to effect certain organic transformations. It is one of the active ingredients and finds application in thermoelectric and piezoelectric materials.
ApplicationLanthanum Oxide, also called Lanthana, high purity Lanthanum Oxide (99.99% to 99.999%) is applied in making special optical glasses to improves the alkali resistance of glass, and is used in La-Ce-Tb phosphors for fluorescent lamps and making special optical glasses, such as infrared-absorbing glass, as well as camera and telescope lenses, Low grade of Lanthanum Oxide is widely used in ceramics and FCC catalyst, and also as raw material for Lanthanum Metal production; Lanthanum Oxide is also used as a grain growth additive during the liquid phase sintering of Silicon Nitride and Zirconium Diboride.
PreparationLanthanum oxide can be produced by direct combustion of lanthanum in oxygen or air. The oxide also may be prepared by decomposition of an oxo salt of lanthanum, such as nitrate, sulfate, carbonate, hydroxide or oxalate.
La(CO3)3•8H2O → La2O3 + 3CO2 + 8H2O
2La2(C2O4)3•9H2O + 3O2 → 2La2O3 + 12CO2 + 18H2O
General DescriptionLanthanum (III) oxide is an alkaline earth oxide, and is a diamagnetic, isostructural analog of neodymium oxide. It is also an efficient recyclable catalyst, and can be used in coupling various aryl halides with aromatic/alkyl thiols.
Flammability and ExplosibilityNon flammable
reaction suitabilityreagent type: catalyst
core: lanthanum
Industrial usesLanthanum oxide (La2O3) has a melting pointof 2250°C, is soluble in acids, and very slightlysoluble in water. This oxide of a rare earth elementoccurs in monazite and bastnasite. It ismarketed as the oxide or as other salts such asthe oxalate, nitrate, or hydrate. It quicklyabsorbs water and CO2 from the atmosphere.Its chief use is as an ingredient in nonsilica,rare element optical glass with oxides of tungsten, tantalum, and thorium. Lanthanumincreases refractive index, decreases dispersion,and is also used in x-ray image intensifyingscreens that speed up x-ray exposure asmuch as two to ten times so that diagnosticdosages may be reduced by as much as 80%with fewer retakes. It is also used in bariumtitanate capacitors.
Lanthanum oxide Preparation Products And Raw materials
Raw materialsExtractant-->Phosphine-->PYROGALLOL RED-->METHYLPHOSPHONIC ACID-->LANTHANUM-->Rare earth micronutrients
Preparation ProductsLanthanum Fluoride
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