| Company Name: |
Energy Chemical |
| Tel: |
400-0056266 |
| Email: |
sales8178@energy-chemical.com |
| Company Name: |
Sigma-Aldrich |
| Tel: |
021-61415566 800-8193336 |
| Email: |
orderCN@merckgroup.com |
|
| | 1-Diphenylphosphino-1'-(di-tert-butylph& Basic information |
| | 1-Diphenylphosphino-1'-(di-tert-butylph& Chemical Properties |
| Melting point | 75-79 °C(lit.) | | form | Powder | | color | yellow to orange | | Sensitive | air sensitive | | InChI | 1S/C17H14P.C13H22P.Fe/c1-3-9-15(10-4-1)18(17-13-7-8-14-17)16-11-5-2-6-12-16;1-12(2,3)14(13(4,5)6)11-9-7-8-10-11;/h1-14H;7-10H,1-6H3; | | InChIKey | GQIMIFFIUZZVMJ-UHFFFAOYSA-N | | SMILES | [Fe].CC(C)(C)P([C]1[CH][CH][CH][CH]1)C(C)(C)C.[CH]2[CH][CH][C]([CH]2)P(c3ccccc3)c4ccccc4 |
| Risk Statements | 36/37/38 | | Safety Statements | 26-37 | | WGK Germany | 3 | | TSCA | No | | Storage Class | 11 - Combustible Solids |
| | 1-Diphenylphosphino-1'-(di-tert-butylph& Usage And Synthesis |
| Uses | Catalyst in microwave-assisted preparation of aryl-alkyl ethers via palladium-catalyzed Hiyama coupling of alkoxysilanes with aryl bromides or aryl chlorides Ligand for catalytic isomerization of methylbutenenitrile via nickel systems Ligand for ruthenium alkylidene complexes for catalysis of metathesis reactions and catalytic norbornene polymerization. | | Uses | - Catalyst in microwave-assisted preparation of aryl-alkyl ethers via palladium-catalyzed Hiyama coupling of alkoxysilanes with aryl bromides or aryl chlorides
- Ligand for catalytic isomerization of methylbutenenitrile via nickel systems
- Ligand for ruthenium alkylidene complexes for catalysis of metathesis reactions and catalytic norbornene polymerization
| | reaction suitability | reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: ligand
reaction type: Coupling Reactions |
| | 1-Diphenylphosphino-1'-(di-tert-butylph& Preparation Products And Raw materials |
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