(1R,2R)-N,N'-Bis(2-acetyl-3-oxo-2-butenylidene)-1,2-dimesitylethylenediaminato cobalt(II)

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(1R,2R)-N,N'-Bis(2-acetyl-3-oxo-2-butenylidene)-1,2-dimesitylethylenediaminato cobalt(II) Basic information

Product Name:	(1R,2R)-N,N'-Bis(2-acetyl-3-oxo-2-butenylidene)-1,2-dimesitylethylenediaminato cobalt(II)
Synonyms:	(R)-AMAC;(R,R)-AMAC;(E)-3-[[(1R,2R)-2-[[(E)-2-acetyl-3-oxidobut-2-enylidene]amino]-1,2-bis(2,4,6-trimethylphenyl)ethyl]iminomethyl]-4-oxopent-2-en-2-olate;(1R,2R)-N,N′-Bis(2-acetyl-3-oxo-2-butenylidene)-1,2-dimesitylethylenediaminato cobalt(II);(1R,2R)-N,N′-Bis(2-acetyl-3-oxo-2-butenylidene)-1,2-dimesitylethylenediaminato Cobalt(II), CAS 361346-80-7;(1R,2R)-N,N'-Bis(2-acetyl-3-oxo-2-butenylidene)-1,2-dimesitylethylenediaminato cobalt(II)
CAS:	361346-80-7
MF:	C32H38CoN2O4
MW:	573.59
EINECS:
Product Categories:	Asymmetric Synthesis;Catalysts for Organic Synthesis;Classes of Metal Compounds;Co (Cobalt) Compounds;Homogeneous Catalysts;Metal Complexes;Synthetic Organic Chemistry;Transition Metal Compounds
Mol File:	361346-80-7.mol

(1R,2R)-N,N'-Bis(2-acetyl-3-oxo-2-butenylidene)-1,2-dimesitylethylenediaminato cobalt(II) Chemical Properties

Melting point	246-250°C
storage temp.	under inert gas (nitrogen or Argon) at 2-8°C
form	solid
Optical Rotation	[α]/D 291°, c = 0.1 in chloroform
InChIKey	PHCQQLMRNZRDJA-ZQBGJXBSSA-L
SMILES	CC(=O)C1=C(C)O[Co]OC(C)=C(\C=N\[C@@H]([C@H](\N=C\1)c2c(C)cc(C)cc2C)c3c(C)cc(C)cc3C)C(C)=O

Safety Information

Hazard Codes	Xn
Risk Statements	20/21/22-36/37/38
Safety Statements	22-24/25-36/37/39
WGK Germany	2
HS Code	2942.00.3500
Storage Class	13 - Non Combustible Solids
Hazard Classifications	Acute Tox. 4 Dermal Acute Tox. 4 Inhalation Acute Tox. 4 Oral Eye Irrit. 2 Skin Irrit. 2 STOT SE 3

MSDS Information

(1R,2R)-N,N'-Bis(2-acetyl-3-oxo-2-butenylidene)-1,2-dimesitylethylenediaminato cobalt(II) Usage And Synthesis

Uses

Schiff base-cobalt complex catalyst for asymmetric borohydride reduction of carbonyl compounds

Catalyst for:

Enantioselective borohydride reduction
Stereoselective preparation of aryl alcohols via asymmetric reduction of aryl ketones with borohydride
Stereoselective borohydride reduction of diketones to diols
Stereoselective preparation of optically active deuterated primary alcohols via enantioselective borodeuteride reduction of aldehydes
Stereoselective preparation of β-hydroxy esters via dynamic kinetic resolution of alkylketo esters with enantioselective borohydride reduction
Chemoselective, diastereoselective, and enantioselective borohydride reduction of 1,3-diketones
Asymmetric synthesis of diarylhydroxypropanones by stereoselective reduction of alkyldiaryldiketones

(1R,2R)-N,N'-Bis(2-acetyl-3-oxo-2-butenylidene)-1,2-dimesitylethylenediaminato cobalt(II) Preparation Products And Raw materials

Tag:(1R,2R)-N,N'-Bis(2-acetyl-3-oxo-2-butenylidene)-1,2-dimesitylethylenediaminato cobalt(II)(361346-80-7) Related Product Information

(1S,2S)-N,N'-Bis(2-acetyl-3-oxo-2-butenylidene)-1,2-dimesitylethylenediaminato cobalt(II) (1R,2R)-N,N'-Bis(2-acetyl-3-oxo-2-butenylidene)-1,2-dimesitylethylenediaminato cobalt(II) meso-1,2-Bis(p-tolyl)ethylenediamine (1R,2R)-1,2-Bis(2,4,6-trimethylphenyl)ethylenediamine (S)-1-Phenyl-2-(p-tolyl)ethylamine Cobalt 1,2-Diphenylethylenediamine Benzenemethanamine,a,2,4-trimethyl-, (aS)- Benzenemethanamine, α,2,4,6-tetramethyl-, (αS)-

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