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- Phenyl-t-butylether
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2026-06-30
- CAS:6669-13-2
- Min. Order: 1kg
- Purity: 99%
- Supply Ability: 10000KGS
- Phenyl-t-butylether
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- $9.80
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2020-01-03
- CAS:6669-13-2
- Min. Order: 1KG
- Purity: 97%-99%
- Supply Ability: 1kg -1000kg
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| | Phenyl-t-butylether Basic information | | Synthesis |
| Product Name: | Phenyl-t-butylether | | Synonyms: | (1,1-Dimethylethoxy)benzene;tert-Butyl phenyl ether, 98%;2-Methyl-2-phenoxypropane;Phenyl tert-butyl ether;tert-Butoxybenzene;Benzene, (1,1-dimethylethoxy)-;Inchi=1/C10H14o/C1-10(2,3)11-9-7-5-4-6-8-9/H4-8H,1-3h;NSC 78717 | | CAS: | 6669-13-2 | | MF: | C10H14O | | MW: | 150.22 | | EINECS: | | | Product Categories: | | | Mol File: | 6669-13-2.mol |  |
| | Phenyl-t-butylether Chemical Properties |
| Melting point | -17--16℃ | | Boiling point | 184°C | | density | 0.924 | | refractive index | 1.488 | | Fp | 184°C | | storage temp. | Sealed in dry,Room Temperature | | Appearance | Colorless to light yellow Liquid | | InChI | InChI=1S/C10H14O/c1-10(2,3)11-9-7-5-4-6-8-9/h4-8H,1-3H3 | | InChIKey | PNKZBZPLRKCVLI-UHFFFAOYSA-N | | SMILES | C1(OC(C)(C)C)=CC=CC=C1 |
| | Phenyl-t-butylether Usage And Synthesis |
| Synthesis | A 4-mL vial was charged with bromobenzene (63 mg, 0.40 mmol), Pd(dba)2 (11.5 mg, 0.0200 mmol), Ph5FcP-(t-Bu)2 (14.2 mg, 0.0200 mmol), and sodium tert-butoxide (47 mg, 0.48 mmol). Anhydrous toluene (2 mL) was added, and the vial was sealed with a cap containing a PTFE septum and removed from the dry box. The reaction mixture was stirred at room temperature for 23 h. The reaction solution was then adsorbed onto silica gel, and the product was isolated by eluting with EtOAc/hexanes (0 to 10% gradient) to give the ether (58 mg, 97%).
Reference: Kataoka, N.; Shelby, Q.; Stambuli, J. P.; Hartwig, J. F. J. Org. Chem. 2002, 67, 5553–5566.
 | | Uses | tert-Butoxybenzene was studied in the analysis of the color and flavor improvement of different starter cultures on northern air-dried sausage. |
| | Phenyl-t-butylether Preparation Products And Raw materials |
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