N-METHYLPIPERIDINE-4-CARBOXAMIDE

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Company Name: J & K SCIENTIFIC LTD.  
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Company Name: Nanjing Chemlin Chemical Co., Ltd  
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Email: info@chemlin.com.cn
Company Name: Chengdu HappySyn Pharmaceutical Technology Co., Ltd.  
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Company Name: Shanghai Raise Chemical Technology Co.,Ltd  
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Company Name: Tcichem, Inc.  
Tel: 13918644899
Email: 81587635@qq.com

N-METHYLPIPERIDINE-4-CARBOXAMIDE manufacturers

N-METHYLPIPERIDINE-4-CARBOXAMIDE Basic information
Product Name:N-METHYLPIPERIDINE-4-CARBOXAMIDE
Synonyms:N-Methyl-4-piperidinecarboxaMide;4-Piperidinecarboxamide, N-methyl-;N-methylpiperidin-4-carboxylic acid amide;N-Methyl-piperidin-4-carboxamide;N-METHYLPIPERIDINE-4-CARBOXAMID
CAS:1903-69-1
MF:C7H14N2O
MW:142.2
EINECS:
Product Categories:
Mol File:1903-69-1.mol
N-METHYLPIPERIDINE-4-CARBOXAMIDE Structure
N-METHYLPIPERIDINE-4-CARBOXAMIDE Chemical Properties
Melting point 123~125℃
Boiling point 318.5±31.0 °C(Predicted)
density 0.997±0.06 g/cm3(Predicted)
pka16.06±0.20(Predicted)
form powder
color Yellow
Safety Information
HazardClass IRRITANT
HS Code 2933399990
MSDS Information
N-METHYLPIPERIDINE-4-CARBOXAMIDE Usage And Synthesis
Synthesis
1-TERT-BUTOXYCARBONYLPIPERIDINE-4-CARBOXYLIC ACIDMETHYL AMIDE

544696-01-7

N-METHYLPIPERIDINE-4-CARBOXAMIDE

1903-69-1

GENERAL STEPS: 1-Boc-4-piperidinyl-N-methylamide (68 mg, 0.28 mmol) was dissolved in methanol (2 mL) and cooled to 0°C. A 1,4-dioxane solution (2 mL) of 4 M hydrogen chloride was slowly added. The reaction mixture was stirred at 0°C for 15 minutes and then gradually warmed to room temperature and continued stirring for 3 hours. After completion of the reaction, the solvent was removed by distillation under reduced pressure. The crude product was purified by SCX-2 column chromatography, eluting first with methanol and then with 0.5 M ammonia in methanol solution to afford N-methylpiperidine-4-carboxamide as a colorless oil (41 mg, 99% yield). The product was detected by infrared spectroscopy (CHCl3) with characteristic absorption peaks of 1308, 2948, 1663, 1525, 1227, 1119 cm-1; mass spectrometry (ESI) analysis showed that the theoretical value of the [M+H]+ ion peak of C7H15N2O was 143.1179 and the measured value was 143.1178.

References[1] Patent: WO2010/41054, 2010, A1. Location in patent: Page/Page column 32
N-METHYLPIPERIDINE-4-CARBOXAMIDE Preparation Products And Raw materials
Raw materials1-TERT-BUTOXYCARBONYLPIPERIDINE-4-CARBOXYLIC ACIDMETHYL AMIDE-->Hydrochloric acid-->Ammonia-->1,4-Dioxane-->Methanol
Tag:N-METHYLPIPERIDINE-4-CARBOXAMIDE(1903-69-1) Related Product Information
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