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Methyl 1-cyclohexene-1-carboxylate

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Methyl 1-cyclohexene-1-carboxylate manufacturers

Methyl 1-cyclohexene-1-carboxylate Basic information
Product Name:Methyl 1-cyclohexene-1-carboxylate
Synonyms:Methyl cyclohex-1-ene-1-carboxylate 98%;1-Cyclohexene-1-carboxylic acid, methyl ester;METHYL 3,4,5,6-TETRAHYDROBENZOATE;METHYL 1-CYCLOHEXENE-1-CARBOXYLATE;METHYL 1-CYCLOHEXENECARBOXYLATE;CYCLOHEXENE-1-CARBOXYLIC ACID METHYL ESTER;CYCLOHEX-1-ENECARBOXYLIC ACID METHYL ESTER;RARECHEM AL BF 0805
CAS:18448-47-0
MF:C8H12O2
MW:140.18
EINECS:242-331-5
Product Categories:C8 to C9;Carbonyl Compounds;Esters;Building Blocks;C8 to C9;Carbonyl Compounds;heterocyclic/Aliphatic series;Aromatic Esters;Chemical Synthesis;Organic Building Blocks
Mol File:18448-47-0.mol
Methyl 1-cyclohexene-1-carboxylate Structure
Methyl 1-cyclohexene-1-carboxylate Chemical Properties
Boiling point 190-192 °C
density 1.028 g/mL at 20 °C(lit.)
refractive index n20/D 1.477
Fp 165 °F
storage temp. Sealed in dry,Room Temperature
form Liquid
color Clear colorless
Water Solubility insoluble
BRN 1071971
InChIInChI=1S/C8H12O2/c1-10-8(9)7-5-3-2-4-6-7/h5H,2-4,6H2,1H3
InChIKeyKXPWRCPEMHIZGU-UHFFFAOYSA-N
SMILESC1(C(OC)=O)CCCCC=1
CAS DataBase Reference18448-47-0(CAS DataBase Reference)
NIST Chemistry ReferenceMethyl 1-cyclohexene-1-carboxylate(18448-47-0)
Safety Information
Safety Statements 23-24/25
WGK Germany 3
10-23
HS Code 29162090
Storage Class10 - Combustible liquids
MSDS Information
ProviderLanguage
SigmaAldrich English
ACROS English
ALFA English
Methyl 1-cyclohexene-1-carboxylate Usage And Synthesis
Chemical Propertiesclear colorless liquid
UsesMethyl 1-cyclohexene-1-carboxylate is used in the diastereoselective synthesis of cis-1,2-dialkenylcyclopropanols and methyl -7,7-dimethyl-9-oxo-1,3,4,4a,6,7,8,9,9b-decahydrodibenzo[b,d]furan-4a-carboxylate.
Synthesis Reference(s)The Journal of Organic Chemistry, 33, p. 1550, 1968 DOI: 10.1021/jo01268a053
Tetrahedron Letters, 17, p. 453, 1976
Methyl 1-cyclohexene-1-carboxylate Preparation Products And Raw materials
Raw materialsCyclohexene-->Formic acid-->Methanol
Preparation Products3-Methoxycyclohexene-->Cyclohexanecarboxylic acid, 2-(aminomethyl)-, methyl ester-->Cyclohexanecarboxylic acid, 2-methyl-, (1S,2R)-
Tag:Methyl 1-cyclohexene-1-carboxylate(18448-47-0) Related Product Information
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