(-)-1,1'-Bis((2S,4S)-2,4-diethylphosphotano)ferrocene

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(-)-1,1'-Bis((2S,4S)-2,4-diethylphosphotano)ferrocene Basic information
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Product Name:(-)-1,1'-Bis((2S,4S)-2,4-diethylphosphotano)ferrocene
Synonyms:(-)-1,1'-Bis[(2S,4S)-2,4-diethylphosphotano)ferrocene: 95% (S,S)-Et-FerroTANE;(-)-1,1'-Bis((2S,4S)-2,4-diethylphosphotano)ferrocene (S,S)-Et-FerroTANE;(S,S)-ET-FERROTANE(TM);Bisdiethylphosphotanoferrocene;(-)-1,1'-Bis((2S,4S)-2,4-diethylphosphotano)ferrocene,min.95%(S,S)-Et-FerroTANE;(-)-1,1'-BIS((2S,4S)-2,4-DIETHYLPHOSPHONATO)FERROCENE,MIN.95%(S,S)-ET-FERROTANE;(-)-1,1'-Bis((2S,4S)-2,4-diethylphosphonato)ferrocene, min. 95% (S,S)-Et-FerroTANE(R);(-)-1,1'-Bis((2S,4S)-2,4-diethylphosphonato)ferrocene, min. 95% (S,S)-Et-FerroTANE
CAS:290347-66-9
MF:C24H36FeP210*
MW:442.34
EINECS:
Product Categories:
Mol File:290347-66-9.mol
(-)-1,1'-Bis((2S,4S)-2,4-diethylphosphotano)ferrocene Structure
(-)-1,1'-Bis((2S,4S)-2,4-diethylphosphotano)ferrocene Chemical Properties
Melting point 76°C
alpha -660° (c 1, heptane)
form Powder
color yellow-orange
Sensitive air sensitive
Safety Information
Risk Statements 36/37/38
Safety Statements 26-36/37/39
MSDS Information
(-)-1,1'-Bis((2S,4S)-2,4-diethylphosphotano)ferrocene Usage And Synthesis
ReactionsLigand for Ir-catalyzed [2+2+2] cycloaddition for enantioselective synthesis of silahelicenes. 2. Ligand for the preparation of (2,3-dihydrobenzofuran-3-yl)-acetic acid derivatives via Rh-catalyzed asymmetric hydrogenation.  Reactions of 290347-66-9
(-)-1,1'-Bis((2S,4S)-2,4-diethylphosphotano)ferrocene Preparation Products And Raw materials
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(-)-1,1'-Bis((2S,4S)-2,4-diethylphosphotane)ferrocene(1,5-cyclooctadiene)rhodium(I)tetrafluoroborate (-)-1,1'-Bis((2S,4S)-2,4-diethylphosphotano)ferrocene