[Tris(2,4-di-tert-butylphenyl)phosphite]gold chloride

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[Tris(2,4-di-tert-butylphenyl)phosphite]gold chloride Basic information
Product Name:[Tris(2,4-di-tert-butylphenyl)phosphite]gold chloride
Synonyms:[Tris(2,4-di-tert-butylphenyl)phosphite]gold chloride;Chloro[tris(2,4-di-tert-butylphenyl)phosphite]gold;Chloro[tris(2,4-di-tert-butylphenyl)phosphite]gold;[tris(2,4-di-tert-Butylphenyl)phosphite]Chloro gold
CAS:915299-24-0
MF:C42H64AuClO3P
MW:880.36
EINECS:
Product Categories:Au
Mol File:915299-24-0.mol
[Tris(2,4-di-tert-butylphenyl)phosphite]gold chloride Structure
[Tris(2,4-di-tert-butylphenyl)phosphite]gold chloride Chemical Properties
Melting point 200-202 °C
storage temp. under inert gas (nitrogen or Argon) at 2–8 °C
form powder
InChIKeyGCWCLHMEYZKZRO-UHFFFAOYSA-M
SMILESCl[Au].CC(C)(C)c1ccc(OP(Oc2ccc(cc2C(C)(C)C)C(C)(C)C)Oc3ccc(cc3C(C)(C)C)C(C)(C)C)c(c1)C(C)(C)C
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38
Safety Statements 26
WGK Germany 3
Storage Class11 - Combustible Solids
Hazard ClassificationsEye Irrit. 2
Skin Irrit. 2
STOT SE 3
MSDS Information
[Tris(2,4-di-tert-butylphenyl)phosphite]gold chloride Usage And Synthesis
UsesGold Catalysts — 21st Century ′Gold Rush′
  • Intermolecular addition of carbon nucleophiles to 1,5 and 1,6 enynes

Catalyst for:
  • [4C+2C] cycloadditions
  • Cis-selective single-cleavagte skeletal cycloisomerization
  • Diastereoselective Au-catalyzed intermolecular cyclopropanation
  • Elucidating the mechanism of "endocyclic" skeletal rearrangement of 1,6-enynes
  • Addition reactions
reaction suitabilitycore: gold
reagent type: catalyst
[Tris(2,4-di-tert-butylphenyl)phosphite]gold chloride Preparation Products And Raw materials
Tag:[Tris(2,4-di-tert-butylphenyl)phosphite]gold chloride(915299-24-0) Related Product Information
Antioxidant 168 Gold(III) chloride dihydrate Bis(2,4-di-tert-butylphenylphosphate Sodium 2,2'-methylene-bis-(4,6-di-tert-butylphenyl)phosphate Ultranox 626 TRIS(ISOPROPYLPHENYL)PHOSPHATE