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| | 2,3-Bis(2,6-di-I-propylphenylimino)butane Basic information | | Reactions |
| Product Name: | 2,3-Bis(2,6-di-I-propylphenylimino)butane | | Synonyms: | 2,3-Bis(2,6-di-i-propylphenylimino)butane,98%;N,N''-(1,2-Dimethyl-1,2-ethanediylidene)-bis-[2,6-bis-(1-methylethyl)-benzen;N,N'-(1,2-Dimethyl-1,2-ethanediylidene)bis(2,6-diisopropylaniline);N,N'-(1,2-Dimethyl-1,2-ethanediylidene)bis[2,6-bis(1-methylethyl)benzenamine];N,N'-(1,2-Dimethylethane-1,2-diylidene)bis(2,6-diisopropylaniline);N,N'-(2,3-Butanediylidene)bis(2,6-diisopropylaniline);N,N'-Bis(2,6-diisopropylphenyl)-2,3-butanediimine;N,N'-Bis(2,6-diisopropylphenyl)butane-2,3-diimine | | CAS: | 74663-77-7 | | MF: | C28H40N2 | | MW: | 404.63 | | EINECS: | | | Product Categories: | Py-N;organic amine;Achiral Nitrogen | | Mol File: | 74663-77-7.mol |  |
| | 2,3-Bis(2,6-di-I-propylphenylimino)butane Chemical Properties |
| Melting point | 104-106°C | | Boiling point | 509.338±60.00 °C(Press: 760.00 Torr)(predicted) | | density | 0.948±0.14 g/cm3(Temp: 25 °C; Press: 760 Torr)(predicted) | | storage temp. | 2-8°C, protect from light, stored under nitrogen | | form | crystal | | pka | 2.453±0.50(predicted) | | color | yellow | | BRN | 6746881 | | InChI | InChI=1S/C28H40N2/c1-17(2)23-13-11-14-24(18(3)4)27(23)29-21(9)22(10)30-28-25(19(5)6)15-12-16-26(28)20(7)8/h11-20H,1-10H3 | | InChIKey | YUFQUBWPYIPRHZ-UHFFFAOYSA-N | | SMILES | C(=NC1=C(C(C)C)C=CC=C1C(C)C)(C)C(=NC1=C(C(C)C)C=CC=C1C(C)C)C |
| Risk Statements | 36/37/38 | | Safety Statements | 26-36/37/39 | | WGK Germany | 3 | | HS Code | 2925.29.6000 | | Storage Class | 13 - Non Combustible Solids | | Hazard Classifications | Aquatic Chronic 4 |
| | 2,3-Bis(2,6-di-I-propylphenylimino)butane Usage And Synthesis |
| Reactions |
- 1. Ligand used in the preparation of highly active metal catalysts for the polymerization of ethylene (ref 1, M=Ni, Pd) and olefins (ref 2, M=Pd; ref 3, M= Hf, Zr)
- Ligand for the iron catalyzed polymerization of styrene acrylate monomers
- Ligand for Yttrium complex that catalysis the ring-opening polymerization of cyclic esters
- Ligand for rare-earth dichloro and bis(alkyl) complexes for isoprene polymerization
- Ligand for cobalt catalyzed alkene hydroboration
- Ligand for nickel catalyzed alkene hydrosilylation
| | Uses | Reactant for synthesis of:
- Lanthanide(II)-alkali sandwich complexes
- Imido-amido Hf complexes
- Alkali metal compounds
- Tetracoordinated molybdenum(II) complexes
Reactant for:
- Complexation of dimethylmagnesium with α-diimines
- Transfer of tin and germanium atoms from N-heterocyclic stannylenes and germylenes to diazadienes
| | reaction suitability | reagent type: ligand |
| | 2,3-Bis(2,6-di-I-propylphenylimino)butane Preparation Products And Raw materials |
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