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| | Lithium diethylamide Basic information |
| | Lithium diethylamide Chemical Properties |
| solubility | sol THF, Et2O, Et2O-hexane mixtures, Et2O-benzene mixtures; insol hydrocarbon solvents | | pka | pKa = 31.7 | | form | solid | | color | off-white to light-orange | | Sensitive | moisture sensitive |
| Hazard Codes | F,C | | Risk Statements | 17-34 | | Safety Statements | 16-26-27-36/37/39-45 | | RIDADR | UN 3393 4.2/PG 1 | | WGK Germany | 3 | | HazardClass | 4.2 | | PackingGroup | I |
| | Lithium diethylamide Usage And Synthesis |
| Uses | Lithium Diethylamide is used as a strong base; nitrogen nucleophile.
| | Synthesis Reference(s) |
1.Normant, H.; Cuvigny, T.; Reisdorf, D. CR(C) 1969, 268, 521.
2. Gaudemar-Bardone, F.; Gaudemar, M. S 1979, 463.
| | Synthesis |
Lithium Diethylamide is synthesized by treating diethylamine with Phenyllithium or n-Butyllithium or, alternatively, by treating diethylamine with Lithium metal in the presence of Hexamethylphosphoric Triamide or an electron acceptor.1,2
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| | Lithium diethylamide Preparation Products And Raw materials |
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