N-METHOXY-N-METHYL(TRIPHENYL-PHOSPHORANYLIDENE)ACETAMIDE

N-METHOXY-N-METHYL(TRIPHENYL-PHOSPHORANYLIDENE)ACETAMIDE Suppliers list
Company Name: Aladdin Scientific
Tel:
Email: tp@aladdinsci.com
Products Intro: Product Name:N-Methoxy-N-methyl(triphenylphosphoranylidene)acetamide
CAS:129986-67-0
Purity:95% Package:$210.9/5g;$800.9/25g;Bulk package Remarks:95%
Company Name: ABCR GmbH & CO. KG
Tel: 49 721 95061 0
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Products Intro:
Company Name: J & K SCIENTIFIC LTD.  
Tel: 18210857532; 18210857532
Email: jkinfo@jkchemical.com
Products Intro: Product Name:N-Methoxy-N-methyl-2-(triphenylphosphoranylidene)acetamide, 98%
CAS:129986-67-0
Purity:98% Package:5GR, 25GR
Company Name: Meryer (Shanghai) Chemical Technology Co., Ltd.  
Tel: 4006356688 18621169109
Email: market03@meryer.com
Products Intro: Product Name:N-Methoxy-N-Methyl-2-(triphenylphosphoranylidene)acetaMide
CAS:129986-67-0
Purity:98% Remarks:39009
Company Name: Energy Chemical  
Tel: 021-021-58432009 400-005-6266
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Products Intro: Product Name:N-METHOXY-N-METHYL(TRIPHENYL-PHOSPHORANYLIDENE)ACETAMIDE
CAS:129986-67-0
Purity:98% Package:25G,5G
N-METHOXY-N-METHYL(TRIPHENYL-PHOSPHORANYLIDENE)ACETAMIDE Basic information
Product Name:N-METHOXY-N-METHYL(TRIPHENYL-PHOSPHORANYLIDENE)ACETAMIDE
Synonyms:N-METHOXY-N-METHYL(TRIPHENYL-PHOSPHORANYLIDENE)ACETAMIDE;N-METHOXY-N-METHYL-2-(TRIPHENYLPHOSPHORANYLIDENE)ACETAMIDE;[N-METHOXYMETHYLAMINOCARBONYLMETHYLENE]-TRIPHENYLPHOSPHORANE;N-Methoxy-N-methyl-2-(triphenylphosphoranylidene)acetamide, 98 %;(N-methoxymethylaminocarbonylmethylene)triphenylphosphoran;N-Methoxy-N-methyl(triphenylphosphoranylidene)acetamide 98%;N-methoxy-N-methyl-2-(triphenyl-l5-phosphanylidene)acetamide;Acetamide, N-methoxy-N-methyl-2-(triphenylphosphoranylidene)-
CAS:129986-67-0
MF:C22H22NO2P
MW:363.39
EINECS:
Product Categories:
Mol File:129986-67-0.mol
N-METHOXY-N-METHYL(TRIPHENYL-PHOSPHORANYLIDENE)ACETAMIDE Structure
N-METHOXY-N-METHYL(TRIPHENYL-PHOSPHORANYLIDENE)ACETAMIDE Chemical Properties
Melting point 183 °C
Boiling point 495.6±28.0 °C(Predicted)
density 1.18±0.1 g/cm3(Predicted)
storage temp. -20°C Freezer, Under inert atmosphere
solubility Chloroform (Slightly), Methanol (Slightly)
form Solid
color Off White to Pale Yellow
BRN 4198472
InChI1S/C22H22NO2P/c1-23(25-2)22(24)18-26(19-12-6-3-7-13-19,20-14-8-4-9-15-20)21-16-10-5-11-17-21/h3-18H,1-2H3
InChIKeyDGBLSOOPDBHHRX-UHFFFAOYSA-N
SMILESCON(C)C(=O)C=P(c1ccccc1)(c2ccccc2)c3ccccc3
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38
Safety Statements 26-36
WGK Germany 3
9
HS Code 29241900
Storage Class11 - Combustible Solids
Hazard ClassificationsEye Irrit. 2
Skin Irrit. 2
STOT SE 3
MSDS Information
ProviderLanguage
SigmaAldrich English
N-METHOXY-N-METHYL(TRIPHENYL-PHOSPHORANYLIDENE)ACETAMIDE Usage And Synthesis
Chemical PropertiesWhite to off-white powder
UsesReactant for:
  • Synthesis of electron-deficient alkenes via stereoselective olefination of N-sulfonyl imines
  • Phosphine-catalyzed asymmetric addition reactions
  • Cysteine-catalyzed enantioselective intramolecular Rauhut-Currier reaction
  • Wittig olefination
  • Synthesis of aigialomycin D, a Protein Kinase inhibitor and a potential anticancer agent
reaction suitabilityreaction type: C-C Bond Formation
N-METHOXY-N-METHYL(TRIPHENYL-PHOSPHORANYLIDENE)ACETAMIDE Preparation Products And Raw materials
Raw materials2-BROMO-N-METHOXY-N-METHYL ACETAMIDE-->2-CHLORO-N-METHOXY-N-METHYLACETAMIDE-->Triphenylphosphine
Tag:N-METHOXY-N-METHYL(TRIPHENYL-PHOSPHORANYLIDENE)ACETAMIDE(129986-67-0) Related Product Information
(FORMYLMETHYLENE)TRIPHENYLPHOSPHORANE N-METHOXY-N-METHYL(TRIPHENYL-PHOSPHORANYLIDENE)ACETAMIDE

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