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Rhodium(III) sulfate

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CAS:10489-46-0
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  • 2021-10-21
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Rhodium(III) sulfate Basic information
Product Name:Rhodium(III) sulfate
Synonyms:RHODIUM SULFATE;RHODIUM(III) SULFATE;rhodium(iii)sulfatesolution;sulfuricacid,rhodium(3++)salt(3:2);dirhodium trisulphate;Rhodium plating solution;RHODIUM(III) SULFATE SOLUTION, CA. 8% (W T/WT) RH IN WATER;Rhodium Sulphate
CAS:10489-46-0
MF:H2O4RhS
MW:200.98
EINECS:234-014-5
Product Categories:chemical reaction,pharm,electronic,materials;Materials Science;Metal and Ceramic Science;Rhodium Salts;Inorganics;Metal and Ceramic Science;Rhodium Salts;Salts
Mol File:10489-46-0.mol
Rhodium(III) sulfate Structure
Rhodium(III) sulfate Chemical Properties
Melting point decomposes at >500℃ [KIR82]
Boiling point 99℃[at 101 325 Pa]
density 1.217 g/mL at 25 °C(lit.)
vapor pressure 21.4hPa at 20℃
RTECS FF9335000
storage temp. under inert gas (nitrogen or Argon) at 2-8°C
solubility water: very soluble(lit.)
form red-yellow solid
color red-yellow
Water Solubility Miscible with water, ethanol and with a 3:1 ethanol/water mixture.
Exposure limitsACGIH: TWA 0.2 mg/m3
OSHA: TWA 1 mg/m3
NIOSH: IDLH 15 mg/m3; TWA 1 mg/m3
InChI1S/H2O4S.Rh/c1-5(2,3)4;/h(H2,1,2,3,4);
InChIKeyNZVSOIFAVIORHD-UHFFFAOYSA-N
SMILES[Rh].O=S(=O)(O)O
CAS DataBase Reference10489-46-0(CAS DataBase Reference)
EPA Substance Registry SystemSulfuric acid, rhodium(3+) salt (3:2) (10489-46-0)
Safety Information
Hazard Codes O,T,C
Risk Statements 49-8-23/24/25-34
Safety Statements 53-23-36/37/39-45
RIDADR UN3264
WGK Germany 3
TSCA TSCA listed
HazardClass 8
PackingGroup III
Storage Class11 - Combustible Solids
Hazard ClassificationsEye Irrit. 2
Skin Irrit. 2
STOT SE 3
MSDS Information
ProviderLanguage
Rhodium(III) sulfate English
SigmaAldrich English
ALFA English
Rhodium(III) sulfate Usage And Synthesis
DescriptionWhen heated to decomposition, this product can emit acid mists and toxic gases (including oxides of sulphur and rhodium compounds). This product is not compatible with bases, halides, water, cyclopentadiene, cyclopentanone, oxime, nitroaryl amines, haxalithium disilicide, phosphorus (III) oxide, chlorine bromine pentafluoride, trifluoride, and oxygen difluoride (OF2). Avoid contact with metals. This product can react with water to generate heat.
DescriptionAttempts to prepare Rhodium(III) sulfate from rhodium hydroxide and sulfuric acid lead to two different products, depending on the conditions. these are yellow rhodium sulfate Rh2(SO4)3 15 H2O and red rhodium sulfate Rh2(SO4 )3 4H2O.
Chemical Propertiesreddish yellow solid; ~8% aqueous solution [ALD94] [KIR82]
UsesRhodium(III) sulfate is used as plating reagents and additives for noble metal. It is also used for fancy plating rhodium in jewellery and horologe. Further, it is used for decorative applications.
General DescriptionRhodium(III) sulfate is an anhydrous metal sulfate that is formed by oxidizing rhodium with concentrated sulphuric acid. It is a red crystal that forms a hydrated solution at high temperatures. It is majorly used in the production of high performance coatings by electroplating technique.
Rhodium(III) sulfate Preparation Products And Raw materials
Tag:Rhodium(III) sulfate(10489-46-0) Related Product Information
Magnesium sulfate heptahydrate Ammonium sulfate Sodium sulfate Magnesium sulfate Dimethyl sulfate Zinc sulphate Sodium thiosulfate Aluminum sulfate Copper(II) sulfate Ferrous sulfate heptahydrate Barium sulfate Rhodium(III) Chloride Rhodium RHODIUM(III) OXIDE HYDRATE Rhodium(III) nitrate dihydrate Rhodium(III) chloride hydrate Rhodium(II) acetate dimer Rhodiumtriphenylacetate