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| | Thianthrenium, 5-ethenyl-, tetrafluoroborate(1-) (1:1) Basic information |
| | Thianthrenium, 5-ethenyl-, tetrafluoroborate(1-) (1:1) Chemical Properties |
| Melting point | 110-112°C | | storage temp. | -20°C | | form | powder | | InChI | 1S/C14H11S2.BF4/c1-2-16-13-9-5-3-7-11(13)15-12-8-4-6-10-14(12)16;2-1(3,4)5/h2-10H,1H2;/q+1;-1 | | InChIKey | FXHBWPNFHMRFKM-UHFFFAOYSA-N | | SMILES | [F-][B+3]([F-])([F-])[F-].S1C=2C=CC=CC2[S+](C=C)C=3C=CC=CC13 |
| WGK Germany | WGK 3 | | Storage Class | 11 - Combustible Solids |
| | Thianthrenium, 5-ethenyl-, tetrafluoroborate(1-) (1:1) Usage And Synthesis |
| Uses | 5-Vinylthianthrenium tetrafluoroborate is a crystalline, shelf-stable vinylating reagent developed by the Ritter Lab. Despite the great functionality of the vinyl group for diversification of target compounds, the selective installation of this moeity has remained challenging. 5-Vinylthianthrenium tetrafluoroborate can perform this otherwise challenging transformation with a broad scope of substrate, including the N-vinylation of heterocycles, vinylation of aryl boronic acids, and the annulation of cyclic and heterocyclic substrates. Additionally, this reagent can be used to enable palladium catalyzed cross-coupling reactions. The functionality of 5-vinylthianthrenium tetrafluoroborate enables the usage of vinyl groups as a versatile tool for further functionalization of many substrates and is a functional tool for many snythetic pathways. | | reaction suitability | reaction type: C-C Bond Formation |
| | Thianthrenium, 5-ethenyl-, tetrafluoroborate(1-) (1:1) Preparation Products And Raw materials |
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