| Company Name: |
Alfa Aesar |
| Tel: |
400-6106006 |
| Email: |
saleschina@alfa-asia.com |
| Company Name: |
Energy Chemical |
| Tel: |
400-0056266 |
| Email: |
sales8178@energy-chemical.com |
|
| | SODIUM TETRACHLOROALUMINATE Basic information |
| | SODIUM TETRACHLOROALUMINATE Chemical Properties |
| Melting point | 185 °C (lit.) | | density | 2.01 g/mL at 25 °C (lit.) | | solubility | soluble in H2O | | form | powder | | color | Pale yellow | | Specific Gravity | 2.01 | | Water Solubility | Soluble in water | | Sensitive | Moisture Sensitive | | Merck | 14,8687 | | InChI | InChI=1S/Al.4ClH.Na/h;4*1H;/q+3;;;;;+1/p-4 | | InChIKey | CMLRNXGMTZKKSR-UHFFFAOYSA-J | | SMILES | [Al-](Cl)(Cl)(Cl)Cl.[Na+] |
| Hazard Codes | C | | Risk Statements | 14-34 | | Safety Statements | 22-26-27-36/37/39-45 | | RIDADR | UN 3262 8/PG 2 | | WGK Germany | 3 | | HazardClass | 8 | | PackingGroup | III | | Storage Class | 8B - Non-combustible corrosive hazardous materials | | Hazard Classifications | Eye Dam. 1
Skin Corr. 1B |
| | SODIUM TETRACHLOROALUMINATE Usage And Synthesis |
| Chemical Properties | yellow hygroscopic powder(s); used as a catalyst for organic reactions [CRC10] [HAW93] | | Uses | Sodium tetrachloroaluminate is used as Friedel-Crafts acylating agent , dehydrating and dehydrogenating agent in organic synthesis. | | Uses | Catalyst for organic reactions. | | Definition | A water-soluble pow-
der used as catalyst in organic reactions. | | reaction suitability | reagent type: catalyst
core: aluminum | | Synthesis | The stoichiometric
amounts of C.P. NaCl and freshly sublimed AlCl3 are introduced into the
pear-shaped part of the reaction vessel.
The filling is done under nitrogen and
the vessel should be very clean and dry.
A melting point capillary is then affixed
underneath the ground joint; the apparatus is evacuated to a high vacuum. Preparation torch-sealed. It is then immersed as
of sodium tetrachloro- deeply as possible in an oil bath at
aluminate. 200-240°C. The AlCl3, which tends to
sublime onto the cool parts of the wall,
is driven back by passing a luminous flame over the condensate
spots. When the flask contents have become a nearly clear melt,
they are poured hot into the side flask of the vessel. The product
solidifies on cooling.
NaCl + A1Cl3 = NaAlCl4 |
| | SODIUM TETRACHLOROALUMINATE Preparation Products And Raw materials |
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