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Sigma-Aldrich |
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| | (9R)-6′-Methoxycinchonan-9-amine trihydrochloride
Basic information | | Reaction |
| Product Name: | (9R)-6′-Methoxycinchonan-9-amine trihydrochloride
| | Synonyms: | (9R)-6′-Methoxycinchonan-9-amine trihydrochloride
;9-epi-9-Amino-9-Deoxyquinidine 3HCl;(8α, 9R)-6'-Methoxycinchonan-9-amine trihydrochloride, min. 90%;9R)-6'-Methoxycinchonan-9-amine trihydrochloride, min. 90%;(8α, 9R)-6'-Methoxycinchonan-9-amine trihydrochloride;(8α, 9R)-6''-Methoxycinchonan-9-amine trihydrochloride;(9R)-6'-Methoxy-cinchonan-9-amineTrihydrochloride;(9R)-6′-Methoxycinchonan-9-amine trihydrochloride | | CAS: | 1391506-12-9 | | MF: | C20H26ClN3O | | MW: | 359.9 | | EINECS: | | | Product Categories: | | | Mol File: | 1391506-12-9.mol |  |
| | (9R)-6′-Methoxycinchonan-9-amine trihydrochloride
Chemical Properties |
| alpha | +62.3° (c=1.0, H2O) | | storage temp. | 2-8°C, protect from light, stored under nitrogen | | form | Powder | | color | white to off-white | | Optical Rotation | [α]/D +4.0±1.0°, c = 1 in 0.1 M HCl | | Stability: | store cold | | InChIKey | GZXDEKGNTLNSGM-BQIOMSPYSA-N | | SMILES | Cl.Cl.Cl.COc1ccc2nccc([C@@H](N)C3C[C@@H]4CCN3C[C@@H]4C=C)c2c1 |
| WGK Germany | 3 | | Storage Class | 13 - Non Combustible Solids |
| | (9R)-6′-Methoxycinchonan-9-amine trihydrochloride
Usage And Synthesis |
| Reaction |
- Aza-Michael reactions on α,β-unsaturated ketones.
- Epoxidation of α,β-unsaturated ketones.
- Epoxidation of α,β-unsaturated aldehydes.
- Nitrocyclopropanation of α,β-unsaturated ketones.
- Diels-Alder reaction.
- Intramolecular aldolization of diketones.
- Friedel-Crafts alkylation of indoles with α,β-unsaturated ketones.
- Friedel-Crafts/amination cascade reactions with a-substituted α,β-unsaturated aldehydes.
- Aziridination of acyclic α,β-unsaturated ketones.
- Aziridination of cyclic α,β-unsaturated ketones.
- Double Michael cascade process.
- α-fluorination of cyclic ketones.
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| | (9R)-6′-Methoxycinchonan-9-amine trihydrochloride
Preparation Products And Raw materials |
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