|
|
| | Dichlofenthion Basic information |
| Product Name: | Dichlofenthion | | Synonyms: | nemacidevc-13;o,o-diaethyl-o-2,4-dichlor-phenyl-monothiophosphat;O,O-Diaethyl-O-2,4-dichlorphenyl-thionophosphat;O,O-Diethyl O-(2,4-dichlorophenyl) thiophosphate;O,O-Diethyl-O-(2,4-dichloor-fenyl)-monothiofosfaat;o,o-diethylo-2,4-dichlorophenylthiophosphate;O,O-Dietil-O-(2,4-dicloro-fenil)-monotiofosfato;v-c1-13 | | CAS: | 97-17-6 | | MF: | C10H13Cl2O3PS | | MW: | 315.15 | | EINECS: | 202-564-5 | | Product Categories: | Alphabetic;D;DIA - DICPesticides&Metabolites;Insecticides;NematicidesPesticides;Organophorous;Pesticides;Alpha sort;DAlphabetic;Pesticides&Metabolites | | Mol File: | 97-17-6.mol |  |
| | Dichlofenthion Chemical Properties |
| Boiling point | bp0.1 164-169° | | density | d20 1.300 | | refractive index | nD25 1.5291 | | Fp | 100 °C | | storage temp. | 0-6°C | | solubility | Chloroform (Slightly), Ethyl Acetate (Slightly) | | form | Liquid | | biological source | rabbit | | Water Solubility | 245ug/L(25 ºC) | | Merck | 13,3069 | | BRN | 1993440 | | Henry's Law Constant | 1.0×10-2 mol/(m3Pa) at 25℃, Duchowicz et al. (2020) | | EPA Substance Registry System | Dichlofenthion (97-17-6) |
| Hazard Codes | Xn,N | | Risk Statements | 22-50/53 | | Safety Statements | 60-61 | | RIDADR | 2783 | | WGK Germany | 3 | | RTECS | TF0350000 | | HazardClass | 6.1(b) | | PackingGroup | III | | HS Code | 29201900 | | Storage Class | 10 - Combustible liquids | | Hazardous Substances Data | 97-17-6(Hazardous Substances Data) | | Toxicity | LD50 in male, female rats (mg/kg): 185, 172 orally; 576, 355 dermally (Gaines, Linder) |
| | Dichlofenthion Usage And Synthesis |
| Description | Dichlofenthion is an organophosphate insecticide. It was previously used to control nematodes and cutworms mainly on ornamental crops, lawns and turf. It has a low aqueous solubility, is quite volatile and mobile in soil. Dichlofenthion is moderately toxic to mammals, a skin, eye and respiratory tract irritant and a sensitiser. It is highly toxic to fish and aquatic invertebrates. | | Chemical Properties | Colorless liquid. Boiling point 164-169°C (1.33×10-2 kPa), relative density 1.320 (20/4°C). Easily soluble in most organic solvents and kerosene, with a solubility of 0.245 ppm in water. | | Uses | Nematocide, insecticide. | | Definition | ChEBI: Dichlofenthion is an organic thiophosphate. | | Production Methods | Dichlofenthion is commercially synthesised through a multi-step process involving the formation of its phosphorothioate ester structure. The production typically begins with the reaction of 2,4-dichlorophenol with diethyl phosphorochloridothioate, forming the active compound. This reaction is carried out under controlled conditions using an organic solvent and a base to neutralise the hydrochloric acid byproduct. | | Mechanism of action | Acetylcholinesterase (AchE) inhibitor | | Safety Profile | Poison by ingestion and
skin contact. A very toxic insecticide.
Mutation data reported. See also ESTERS
and PARATHION. When heated to
decomposition it emits very toxic fumes of
POx, SOx, and Cl-. | | Pesticide Type | Insecticide |
| | Dichlofenthion Preparation Products And Raw materials |
|