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| | 2-CHLORO-1,3,2-BENZODIOXABOROLE Basic information |
| | 2-CHLORO-1,3,2-BENZODIOXABOROLE Chemical Properties |
| Melting point | 56-58 °C (lit.) | | Boiling point | 64 °C(Press: 10 Torr) | | density | 1.31±0.1 g/cm3(Predicted) | | Fp | 140 °F | | storage temp. | 2-8°C | | form | powder to crystal | | color | White to Light yellow to Light red | | BRN | 2093985 | | InChI | 1S/C6H4BClO2/c8-7-9-5-3-1-2-4-6(5)10-7/h1-4H | | InChIKey | AZYGEWXDKHFOKB-UHFFFAOYSA-N | | SMILES | Clb1oc2ccccc2o1 |
| Hazard Codes | F,C | | Risk Statements | 11-14-34-37 | | Safety Statements | 16-26-36/37/39-45 | | RIDADR | UN 2925 4.1/PG 2 | | WGK Germany | 3 | | F | 10-23 | | HS Code | 2915.40.5050 | | HazardClass | 8 | | PackingGroup | II | | Storage Class | 4.1B - Flammable solid hazardous materials | | Hazard Classifications | Flam. Sol. 1
Skin Corr. 1B
STOT SE 3 |
| | 2-CHLORO-1,3,2-BENZODIOXABOROLE Usage And Synthesis |
| Uses | B-Chlorocatecholborane can be used:
- To prepare 2-arachidonoylglycerol by acetal cleavage of cis-arachidonoylbenzylidene glycerol.
- To prepare metal boryl complexes (Rh and Ir complexes) through oxidative addition.
- To remove the trityl group in one of the key steps for the synthesis of ()-dictyostatin.
| | General Description | B-Chlorocatecholborane is a boron reagent and a Lewis acid, known to facilitate the borylative cyclization of alkynes to yield the borylated heterocycles. It is also used in the preparation of lactones, and thiophenes. |
| | 2-CHLORO-1,3,2-BENZODIOXABOROLE Preparation Products And Raw materials |
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