4-hydroxynaphthalene-2-sulphonic acid

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4-hydroxynaphthalene-2-sulphonic acid Basic information
Product Name:4-hydroxynaphthalene-2-sulphonic acid
Synonyms:4-hydroxynaphthalene-2-sulphonic acid;4-hydroxynaphthalene-2-sulfonic acid;4-Hydroxy-2-naphthalenesulfonic acid;2-Naphthalenesulfonic acid, 4-hydroxy-
CAS:3771-14-0
MF:C10H8O4S
MW:224.23
EINECS:223-212-7
Product Categories:
Mol File:3771-14-0.mol
4-hydroxynaphthalene-2-sulphonic acid Structure
4-hydroxynaphthalene-2-sulphonic acid Chemical Properties
density 1.549±0.06 g/cm3(Predicted)
storage temp. 2-8°C, stored under nitrogen, away from moisture
pka0.15±0.40(Predicted)
AppearanceWhite to off-white Solid
EPA Substance Registry System2-Naphthalenesulfonic acid, 4-hydroxy- (3771-14-0)
Safety Information
TSCA TSCA listed
MSDS Information
4-hydroxynaphthalene-2-sulphonic acid Usage And Synthesis
Chemical Properties1-Hydroxynaphthalene-3-sulfonic acid [3771-14-0]. (4-hydroxynaphthalene-2- sulfonic acid), C10H8O4S, Mr 224.2, and its salts are very soluble in water. Coupling with diazo compounds occurs in the 2-position with weak diazo compounds, but in the 4-position with strong diazo compounds such as diazotized nitroanilines. Heating with ammonia at 170℃ gives 1,3-naphthalenediamine.
Uses1-Hydroxynaphthalene-3-sulfonic acid is used as a coupling component for the production of direct dyes.
Preparation1-Aminonaphthalene-3-sulfonic acid is heated with dilute sulfuric acid by using high-pressure steam to maintain a pressure of 1 MPa for 20 h. After cooling, screening, and adding salt to the hot liquor, the sodium salt crystallizes on cooling and is isolated in 80 % yield.
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