中文名:(S)-(-)-2, 2-双(二对甲苯基膦)-1,1-二联萘
英文名:(S)-(-)-2,2'-Bis(di-p-tolylphosphino)-1,1'-binaphthyl
纯度:≥98%
货号:S115619
Cas号:100165-88-6
存储温度:充氩
运输条件:常规运输
产品介绍:
(S)-T-BINAP reacts with silver nitrate to form (S)-Tol-BINAP·AgNO3, which can catalyze the enantioselective allylation reaction of aldehydes to form enantiopure secondary alcohols. It may be used as a chiral ligand in the palladium catalyzed asymmetric double carbohydroamination of iodoarenes to form α-aminoamides.It can also catalyze the asymmetric N-allylation reaction of ortho-tert-butylanilide derivatives with diallyl carbonate to form chiral N-allyl ortho-tert-butylanilides.
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