ChemicalBook
Chemical Safety Data Sheet MSDS / SDS

BORANE-N,N-DIETHYLANILINE COMPLEX

Revision Date:2026-03-21Revision Number:1

SECTION 1: Identification of the substance/mixture and of the company/undertaking

Product identifier

  • Product name: BORANE-N,N-DIETHYLANILINE COMPLEX
  • CBnumber: CB1196348
  • CAS: 13289-97-9
  • EINECS Number: 236-305-2
  • Synonyms: N,N-DIETHYLANILINE BORANE

Relevant identified uses of the substance or mixture and uses advised against

  • Relevant identified uses: For R&D use only. Not for medicinal, household or other use.
  • Uses advised against: none

Company Identification

  • Company: Chemicalbook
  • Address: Building 1, Huihuang International, Shangdi 10th Street, Haidian District, Beijing
  • Telephone: 010-86108875

SECTION 2: Hazards identification

GHS Label elements, including precautionary statements

  • Symbol(GHS)
  • Signal wordDanger
Precautionary statements
P422 Store contents under …
P231+P232 Handle under inert gas. Protect from moisture.
P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
Hazard statements
H261 In contact with water releases flammable gas
H225 Highly Flammable liquid and vapour

SECTION 3: Composition/information on ingredients

Substance

  • Product name: BORANE-N,N-DIETHYLANILINE COMPLEX
  • Synonyms: N,N-DIETHYLANILINE BORANE
  • CAS: 13289-97-9
  • EC number: 236-305-2
  • MF: C10H18BN
  • MW: 163.07

SECTION 4: First aid measures

General advice

Show this safety data sheet to the doctor in attend- ance.

If inhaled

After inhalation: fresh air.

In case of skin contact

In case of skin contact: Take off immediately all contaminated clothing. Rinse skin with water/ shower.

In case of eye contact

After eye contact: rinse out with plenty of water. Call in ophthalmologist. Remove contact lenses.

If swallowed

After swallowing: immediately make victim drink water (two glasses at most).

Most important symptoms and effects, both acute and delayed

The most important known symptoms and effects are described in the labelling (see section 2) and/or in section 11

Protection of first-aiders

For personal protection see section 8.

Notes to physician

No data available

SECTION 5: Firefighting measures

Suitable extinguishing media

Carbon dioxide (CO2) Dry powder

Unsuitable extinguishing media

Water Foam

Specific hazards during fire fighting

Combustible. Pay attention to flashback. Vapours are heavier than air and may spread along floors. May not get in touch with: Water Development of hazardous combustion gases or vapours possible in the event of fire. Forms explosive mixtures with air at ambient temper- atures.

Hazardous combustion products

Carbon oxides Nitrogen oxides (NOx) Borane/boron oxides

Specific extinguishing methods

Remove container from danger zone and cool with water. Suppress (knock down) gases/vapours/mists with a water spray jet. Prevent fire extinguishing water from contaminating surface water or the ground water system.

Special protective equipment for fire-fighters

In the event of fire, wear self-contained breathing apparatus.

NFPA 704

2
3
3
HEALTH 2 Intense or continued but not chronic exposure could cause temporary incapacitation or possible residual injury (e.g. diethyl ether, ammonium phosphate, iodine)
FIRE 3 Liquids and solids (including finely divided suspended solids) that can be ignited under almost all ambient temperature conditions . Liquids having a flash point below 22.8 °C (73 °F) and having a boiling point at or above 37.8 °C (100 °F) or having a flash point between 22.8 and 37.8 °C (73 and 100 °F). (e.g. gasoline, acetone)
REACT 3 Capable of detonation or explosive decomposition but requires a strong initiating source, must be heated under confinement before initiation, reacts explosively with water, or will detonate if severely shocked (e.g. ammonium nitrate, cesium, hydrogen peroxide)
SPEC. HAZ.

SECTION 6: Accidental release measures

Personal precautions, protective equipment and emergency procedures

Advice for non-emergency personnel: Do not breathe vapours, aerosols. Avoid substance contact. Ensure adequate ventilation. Keep away from heat and sources of ignition. Evacuate the danger area, observe emergency procedures, consult an expert. Advice for emergency responders: For personal protection see section 8.

Environmental precautions

Do not let product enter drains. Risk of explosion.

Methods and materials for containment and cleaning up

Cover drains. Collect, bind, and pump off spills. Observe possible material restrictions (see sections 7 and 10). Take up with liquid-absorbent material (e.g. Chemizorb® ). Dispose of properly. Clean up affected area.

SECTION 7: Handling and storage

Handling

Advice on protection against fire and explosion
Keep away from open flames, hot surfaces and sources of ignition. Take precautionary measures against static discharge.
Advice on safe handling
Keep workplace dry. Do not allow product to come into contact with water.
Avoidance of contact
Strong oxidizing agents acids Reacts violently with water.

Storage

Further information on storage conditions
Tightly closed. Keep away from heat and sources of ignition.
Materials to avoid
Never allow product to get in contact with water during storage.
Storage class
4.3, Hazardous materials, which set free flammable gases upon contact with water
Recommended storage temperature
Recommended storage temperature see product label.
Further information on storage stability
Vent periodically. Over time, pressure may increase causing containers to burst Handle and open container with care. Handle and store under inert gas.
Packaging material
Suitable material: Mild Steel Drum

SECTION 8: Exposure controls/personal protection

Ingredients with workplace control parameters

Contains no substances with occupational exposure limit values.

Engineering measures

No data available

Personal protective equipment

Respiratory protection
required when vapours/aerosols are generated.
Our recommendations on filtering respiratory protection are based on the following standards: DIN EN 143, DIN 14387 and other accompanying standards relating to the used respiratory protection system.
Recommended Filter type
Filter type ABEK
The entrepeneur has to ensure that maintenance, cleaning and testing of respiratory protective devices are carried out according to the instructions of the producer. These measures have to be properly documented.
Eye/face protection
Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU).
Safety glasses
Skin and body protection
Flame retardant antistatic protective clothing.
Hand protection
Remarks
required
Hygiene measures
Change contaminated clothing. Wash hands after working with substance.

SECTION 9: Physical and chemical properties

Information on basic physicochemical properties

  • Physical stateLiquid
  • Particle characteristics Particle sizeNo data available
  • Molecular weight163.07 g/mol
  • Oxidizing propertiesNo data available
  • Explosive propertiesNo data available
  • Flow timeNo data available
  • Viscosity, kinematicNo data available
  • Viscosity, dynamicNo data available
  • Decomposition temperatureNo data available
  • Autoignition temperatureNo data available
  • Partition coefficient: n-octanol/waterNo data available
  • Water solubilityMAY DECOMPOSE
  • Density0.917 g/mL (25 °C)
    Method: lit.
  • Relative density0.917 g/mL at 25 °C(lit.)
  • Relative vapor densityNo data available
  • Vapor pressureNo data available
  • Lower explosion limit / Lower flammability limitNo data available
  • Upper explosion limit / Upper flammability limitNo data available
  • Burning rateNo data available
  • Flammability (liquids)No data available
  • Flammability (solid, gas)No data available
  • Evaporation rateNo data available
  • Flash point21 °C
    Method: closed cup
  • Boiling point/boiling rangeNo data available
  • Melting point/ range-30 °C
    Method: lit.
  • pHNo data available
  • Odor ThresholdNo data available
  • OdorNo data available
  • ColorClear colorless to yellow
  • Appearanceliquid

SECTION 10: Stability and reactivity

Reactivity

Vapours may form explosive mixture with air.

Chemical stability

sensitive to moisture

Possibility of hazardous reactions

No data available

Conditions to avoid

Do not allow water to enter container because of violent reaction. Warming. Moisture.

Incompatible materials

Strong oxidizing agents acids Reacts violently with water.

Hazardous decomposition products

In the event of fire: see section 5

SECTION 11: Toxicological information

11.1 Information on toxicological effects

Acute toxicity
Oral: No data available
Inhalation: No data available
Dermal: No data available
Skin corrosion/irritation
Remarks: No data available
Serious eye damage/eye irritation
Remarks: No data available
Respiratory or skin sensitization
Classified based on available data. For more details, see section 2
Germ cell mutagenicity
Classified based on available data. For more details, see section 2
Carcinogenicity
Classified based on available data. For more details, see section 2
Reproductive toxicity
Classified based on available data. For more details, see section 2
Specific target organ toxicity - single exposure
Classified based on available data. For more details, see section 2
Specific target organ toxicity - repeated exposure
Classified based on available data. For more details, see section 2
Aspiration hazard
Classified based on available data. For more details, see section 2

11.2 Additional Information

To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

SECTION 12: Ecological information

Ecotoxicity

Components:

(N,N-Diethylaniline)trihydroboron:

Toxicity to fish
Remarks: No data available

Persistence and degradability

Components:

(N,N-Diethylaniline)trihydroboron:

Biodegradability
Remarks: No data available

Bioaccumulative potential

Components:

(N,N-Diethylaniline)trihydroboron:

Bioaccumulation
Remarks: No data available

Mobility in soil

Components:

(N,N-Diethylaniline)trihydroboron:

Stability in soil
Remarks: No data available

Other adverse effects

Components:

(N,N-Diethylaniline)trihydroboron:

Additional ecological information
No data available

SECTION 13: Disposal considerations

Disposal methods

Waste from residues
Offer surplus and non-recyclable solutions to a licensed disposal company.

SECTION 14: Transport information

International Regulations

IATA-DGR

UN/ID No. : UN 3398
Proper shipping name : Organometallic substance, liquid, water-reactive ((N,N-Diethylaniline)trihydroboron)
Class : 4.3
Packing group : II
Labels : Division 4.3 - Substances which in contact with water emit flammable gases
Packing instruction (cargo aircraft) : 481
Packing instruction (passenger aircraft) : 478

IMDG-Code

UN number : UN 3398
Proper shipping name : ORGANOMETALLIC SUBSTANCE, LIQUID, WATERREACTIVE ((N,N-Diethylaniline)trihydroboron)
Class : 4.3
Packing group : II
Labels : 4.3
EmS Code : F-G, S-N
Marine pollutant : no

Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code

Not applicable for product as supplied.

National Regulations

JT/T 617

UN number : UN 3398
Proper shipping name : ORGANOMETALLIC SUBSTANCE, LIQUID, WATERREACTIVE ((N,N-Diethylaniline)trihydroboron)
Class : 4.3
Packing group : II
Labels : 4.3
Environmentally hazardous : no

Special precautions for user

The transport classification(s) provided herein are for informational purposes only, and solely based upon the properties of the unpackaged material as it is described within this Safety Data Sheet. Transportation classifications may vary by mode of transportation, package sizes, and variations in regional or country regulations.

SECTION 15: Regulatory information

Downstream users need to comply with the conditions of safe use of the chemical, understand the environmental and health hazard and risk management measures identified on the SDS as well as the local/national regulations concerning the chemical.

National regulatory information

Regulations on Safety Management of Hazardous Chemicals

Catalogue of Hazardous Chemicals

Identification of Major Hazard Installations for Hazardous Chemicals (GB 18218)

No. / Code Chemical name / Category Threshold quantity

W5.3 Flammable liquids 1,000 t

W11 Substances and mixtures which in 200 t contact with water, emit flammable gases

Hazardous Chemicals for Priority Management

Listed under SAWS

Regulation of Environmental Management on the First Import of Chemicals and the Import and Export of Toxic Chemicals

China Severely Restricted Toxic Chemicals for Import and Export

Listed

Measures on the Environmental Administration of New Chemical Substances Registration

Registration/Notification number

B1A222223521

SECTION 16: Other information

Full text of other abbreviations

AIIC - Australian Inventory of Industrial Chemicals
ANTT - National Agency forTransport by Land of Brazil
ASTM - American Society for the Testing of Materials
bw - Body weight
CMR - Carcinogen, Mutagen or Reproductive Toxicant
DIN -Standard of the German Institute for Standardisation
DSL - Domestic SubstancesList (Canada)
ECx - Concentration associated with x% response
ELx - Loading rate associated with x% response
EmS - Emergency Schedule
ENCS - Existing and NewChemical Substances (Japan)
ErCx - Concentration associated with x% growth rate response
ERG - Emergency Response Guide
GHS - Globally Harmonised System
GLP - Good Laboratory Practice
IARC - International Agency for Research on Can- cer
IATA - International Air Transport Association
IBC - International Code for theConstruction and Equipment of Ships carrying Dangerous Chemicals in Bulk
IC50 -Half maximal inhibitory concentration
ICAO - International Civil Aviation Organiza- tion
IECSC - Inventory of Existing Chemical Substances in China
IMDG - Interna- tional Maritime Dangerous Goods
IMO - International Maritime Organisation
ISHL -Industrial Safety and Health Law (Japan)
ISO - International Organisation forStandardisation
KECI - Korea Existing Chemicals Inventory
LC50 - Lethal Concen- tration to 50 % of a test population
LD50 - Lethal Dose to 50% of a test population (Median Lethal Dose)
MARPOL - International Convention for the Prevention of Pol- lution from Ships
MERCOSUR - The Agreement for the Facilitation of the Transport of Dangerous Goods
n.o.s. - Not Otherwise Specified
Nch - Chilean Norm
NO(A)EC - No Observed (Adverse) Effect Concentration
NO(A)EL - No Observed (Adverse) Ef- fect Level
NOELR - No Observable Effect Loading Rate
NOM - Official MexicanNorm
NTP - National Toxicology Program
NZIoC - New Zealand Inventory of Chem- icals
OECD - Organisation for Economic Co-operation and Development
OPPTS - Of- fice of Chemical Safety and Pollution Prevention
PBT - Persistent, Bioaccumulative and Toxic substance
PICCS - Philippines Inventory of Chemicals and Chemical Sub- stances
(Q)SAR - (Quantitative) Structure Activity Relationship
REACH - Regulation (EC) No 1907/2006 of the European Parliament and of the Council concerning theRegistration, Evaluation, Authorisation and Restriction of Chemicals
SADT - Self-Accelerating Decomposition Temperature
SDS - Safety Data Sheet
TCSI - TaiwanChemical Substance Inventory
TDG - Transportation of Dangerous Goods
TECI -Thailand Existing Chemicals Inventory
TSCA - Toxic Substances Control Act (UnitedStates)
UN - United Nations
UNRTDG - United Nations Recommendations on theTransport of Dangerous Goods
vPvB - Very Persistent and Very Bioaccumulative
WHMIS - Workplace Hazardous Materials Information System
Disclaimer:

The information in this MSDS is only applicable to the specified product, unless otherwise specified, it is not applicable to the mixture of this product and other substances. This MSDS only provides information on the safety of the product for those who have received the appropriate professional training for the user of the product. Users of this MSDS must make independent judgments on the applicability of this SDS. The authors of this MSDS will not be held responsible for any harm caused by the use of this MSDS.

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