Chemical Safety Data Sheet MSDS / SDS
PHENYLTRICHLOROGERMANE
Revision Date:2026-03-21Revision Number:1
Product identifier
- Product name: PHENYLTRICHLOROGERMANE
- CBnumber: CB6113737
- CAS: 1074-29-9
- EINECS Number: 214-039-8
- Synonyms: NSC 269585;Trichlorophenylgermanium
Relevant identified uses of the substance or mixture and uses advised against
- Relevant identified uses: For R&D use only. Not for medicinal, household or other use.
- Uses advised against: none
Company Identification
- Company: Chemicalbook
- Address: Building 1, Huihuang International, Shangdi 10th Street, Haidian District, Beijing
- Telephone: 010-86108875
GHS Label elements, including precautionary statements
-
Symbol(GHS)
- Signal wordDanger
P310 Immediately call a POISON CENTER or doctor/physician.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
Hazard statements
H314 Causes severe skin burns and eye damage
Substance
- Product name: PHENYLTRICHLOROGERMANE
- Synonyms: NSC 269585;Trichlorophenylgermanium
- CAS: 1074-29-9
- EC number: 214-039-8
- MF: C6H5Cl3Ge
- MW: 256.1
4.1 Description of first-aid measures
General adviceConsult a physician. Show this material safety data sheet to the doctor in attendance.
If inhaled
If breathed in, move person into fresh air. If not breathing, give artificial respiration.
Consult a physician.
In case of skin contact
Consult a physician.
Take off contaminated clothing and shoes immediately. Wash off with soap and plenty of water. Consult a physician.
In case of eye contact
Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician.
If swallowed
Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician.
4.2 Most important symptoms and effects, both acute and delayed
The most important known symptoms and effects are described in the labelling (see section 2) and/or in section 11
4.3 Indication of any immediate medical attention and special treatment needed
No data available
5.1 Extinguishing media
Suitable extinguishing mediaUse water spray, alcohol-resistant foam, dry chemical or carbon dioxide.
5.2 Special hazards arising from the substance or mixture
Carbon oxides
Hydrogen chloride gas
Germanium oxides
Hydrogen chloride gas
Germanium oxides
5.3 Advice for firefighters
Wear self-contained breathing apparatus for firefighting if necessary.
5.4 Further information
No data available
6.1 Personal precautions, protective equipment and emergency procedures
Use personal protective equipment. Avoid breathing vapors, mist or gas. Ensure adequate ventilation. Evacuate personnel to safe areas.
For personal protection see section 8.
For personal protection see section 8.
6.2 Environmental precautions
Do not let product enter drains.
6.3 Methods and materials for containment and cleaning up
Soak up with inert absorbent material and dispose of as hazardous waste. Keep in suitable, closed containers for disposal.
6.4 Reference to other sections
For disposal see section 13.
7.1 Precautions for safe handling
Advice on safe handlingAvoid contact with skin and eyes. Avoid inhalation of vapor or mist.
Hygiene measures
Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at the end of workday.
For precautions see section 2.2.
For precautions see section 2.2.
7.2 Conditions for safe storage, including any incompatibilities
Storage conditionsStore in cool place. Keep container tightly closed in a dry and well-ventilated place.
Containers which are opened must be carefully resealed and kept upright to prevent leakage.
Moisture sensitive.
Storage class
Containers which are opened must be carefully resealed and kept upright to prevent leakage.
Moisture sensitive.
Storage class (TRGS 510): 8A: Combustible, corrosive hazardous materials
7.3 Specific end use(s)
Apart from the uses mentioned in section 1.2 no other specific uses are stipulated
8.1 Control parameters
Ingredients with workplace control parameters8.2 Exposure controls
Personal protective equipmentEye/face protection
Tightly fitting safety goggles. Faceshield (8-inch minimum). Use equipment for eye protection tested and approved under appropriate government standards such as
NIOSH (US) or EN 166(EU).
NIOSH (US) or EN 166(EU).
Skin protection
Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique (without touching glove's outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Wash and dry hands.
The selected protective gloves have to satisfy the specifications of Regulation (EU) 2016/425 and the standard EN 374 derived from it.
The selected protective gloves have to satisfy the specifications of Regulation (EU) 2016/425 and the standard EN 374 derived from it.
Body Protection
Complete suit protecting against chemicals, The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace.
Respiratory protection
Where risk assessment shows air-purifying respirators are appropriate use a full- face respirator with multi-purpose combination (US) or type ABEK (EN 14387) respirator cartridges as a backup to engineering controls. If the respirator is the sole means of protection, use a full-face supplied air respirator. Use respirators and components tested and approved under appropriate government standards such as
NIOSH (US) or CEN (EU).
NIOSH (US) or CEN (EU).
Control of environmental exposure
Do not let product enter drains.
Information on basic physicochemical properties
- a) AppearanceForm: liquid
Color: colorless - b) OdorNo data available
- c) Odor ThresholdNo data available
- d) pHNo data available
- e) Melting point/freezing pointNo data available
- f) Initial boiling point and boiling range105 - 106 °C at 16 hPa - lit.
- g) Flash point113 °C - closed cup
- h) Evaporation rateNo data available
- i) Flammability (solid, gas)No data available
- j) Upper/lower flammability or explosive limitsNo data available
- k) Vapor pressureNo data available
- l) Vapor densityNo data available
- m) Density1,584 g/cm3 at 25 °C - lit.
- Relative density1.584 g/mL at 25 °C(lit.)
- n) Water solubilityNo data available
- o) Partition coefficient n-octanol/waterNo data available
- p) Autoignition temperatureNo data available
- q) Decomposition temperatureNo data available
- r) ViscosityViscosity, kinematic: No data available
Viscosity, dynamic: No data available - s) Explosive propertiesNo data available
- t) Oxidizing propertiesNo data available
- Physical stateliquid
9.2 Other safety information
No data available
10.1 Reactivity
No data available
10.2 Chemical stability
Stable under recommended storage conditions.
10.3 Possibility of hazardous reactions
No data available
10.4 Conditions to avoid
No data available
10.5 Incompatible materials
Strong oxidizing agents
10.6 Hazardous decomposition products
In the event of fire: see section 5
11.1 Information on toxicological effects
Acute toxicityOral: No data available
LC50 Inhalation - 4 h - 11 mg/l (Acute toxicity estimate)
LD50 Dermal - 1.100 mg/kg
Skin corrosion/irritation
LC50 Inhalation - 4 h - 11 mg/l (Acute toxicity estimate)
LD50 Dermal - 1.100 mg/kg
Classified based on available data. For more details, see section 2
Serious eye damage/eye irritation
Classified based on available data. For more details, see section 2
Respiratory or skin sensitization
Classified based on available data. For more details, see section 2
Germ cell mutagenicity
Classified based on available data. For more details, see section 2
Carcinogenicity
Classified based on available data. For more details, see section 2
Reproductive toxicity
Classified based on available data. For more details, see section 2
Specific target organ toxicity - single exposure
Classified based on available data. For more details, see section 2
Specific target organ toxicity - repeated exposure
Classified based on available data. For more details, see section 2
Aspiration hazard
Classified based on available data. For more details, see section 2
11.2 Additional Information
Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin., spasm, inflammation and edema of the larynx, spasm, inflammation and edema of the bronchi, pneumonitis, pulmonary edema, burning sensation, Cough, wheezing, laryngitis, Shortness of breath, Headache, Nausea
12.1 Toxicity
No data available
12.2 Persistence and degradability
No data available
12.3 Bioaccumulative potential
No data available
12.4 Mobility in soil
No data available
12.5 Results of PBT and vPvB assessment
This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.
12.6 Other adverse effects
No data available
13.1 Waste treatment methods
Product
Offer surplus and non-recyclable solutions to a licensed disposal company.
Contaminated packaging
Offer surplus and non-recyclable solutions to a licensed disposal company.
Dispose of as unused product.
14.1 UN number
ADR/RID: 3265
IMDG: 3265
IATA: 3265
IMDG: 3265
IATA: 3265
14.2 UN proper shipping name
ADR/RID: CORROSIVE LIQUID, ACIDIC, ORGANIC, N.O.S. (Trichlorophenylgermane)
IMDG: CORROSIVE LIQUID, ACIDIC, ORGANIC, N.O.S. (Trichlorophenylgermane)
IATA: Corrosive liquid, acidic, organic, n.o.s. (Trichlorophenylgermane)
IMDG: CORROSIVE LIQUID, ACIDIC, ORGANIC, N.O.S. (Trichlorophenylgermane)
IATA: Corrosive liquid, acidic, organic, n.o.s. (Trichlorophenylgermane)
14.3 Transport hazard class(es)
ADR/RID: 8
IMDG: 8
IATA: 8
IMDG: 8
IATA: 8
14.4 Packaging group
ADR/RID: II
IMDG: II
IATA: II
IMDG: II
IATA: II
14.5 Environmental hazards
ADR/RID: no
IMDG Marine pollutant: no
IATA: no
IMDG Marine pollutant: no
IATA: no
14.6 Special precautions for user
No data available
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
This material safety data sheet complies with the requirements of Regulation (EC) No.
1907/2006.
1907/2006.
15.2 Chemical Safety Assessment
For this product a chemical safety assessment was not carried out
Abbreviations and acronyms
CAS: Chemical Abstracts Service
TWA: Time-Weighted Average
STEL: Short-Term Exposure Limit
LD50: Lethal Dose 50%
LC50: Lethal Concentration 50%
EC50: Effective Concentration 50%
PEL: Permissible Exposure Limit
TLV: Threshold Limit Value
IMDG: International Maritime Dangerous Goods Code
IATA: International Air Transport Association
ADR: European Agreement concerning the International Carriage of Dangerous Goods by Road
DOT: US Department of Transportation
NFPA: National Fire Protection Association
NIOSH: National Institute for Occupational Safety and Health
OSHA: Occupational Safety and Health Administration
TWA: Time-Weighted Average
STEL: Short-Term Exposure Limit
LD50: Lethal Dose 50%
LC50: Lethal Concentration 50%
EC50: Effective Concentration 50%
PEL: Permissible Exposure Limit
TLV: Threshold Limit Value
IMDG: International Maritime Dangerous Goods Code
IATA: International Air Transport Association
ADR: European Agreement concerning the International Carriage of Dangerous Goods by Road
DOT: US Department of Transportation
NFPA: National Fire Protection Association
NIOSH: National Institute for Occupational Safety and Health
OSHA: Occupational Safety and Health Administration
Disclaimer:
The information in this MSDS is only applicable to the specified product, unless otherwise specified, it is not applicable to the mixture of this product and other substances. This MSDS only provides information on the safety of the product for those who have received the appropriate professional training for the user of the product. Users of this MSDS must make independent judgments on the applicability of this SDS. The authors of this MSDS will not be held responsible for any harm caused by the use of this MSDS.