ChemicalBook--->CAS DataBase List--->1066-51-9

1066-51-9

1066-51-9 Structure

1066-51-9 Structure
IdentificationMore
[Name]

(Aminomethyl)phosphonic acid
[CAS]

1066-51-9
[Synonyms]

1-AMINO-METHYLPHOSPHONIC ACID
(AMINOMETHYL)PHOSPHONIC ACID
AMPA
H-AMEPO-(OH)2
H-GLYP-(OH)2
Phosphaglycine
(aminomethyl)phosphonic
AMINOMETHYL PHOSPHONIC ACID, 100MG, NEAT
AMINOMETHYLPHOSPHONATE
(Aminomethyl)phosphonic acid, 98 %
[EINECS(EC#)]

623-325-5
[Molecular Formula]

CH6NO3P
[MDL Number]

MFCD00008105
[Molecular Weight]

111.04
[MOL File]

1066-51-9.mol
Questions And AnswerBack Directory
[Synthesis]

Add 4.81 g of diethyl (aminomethyl)phosphonate to a 500 mL reaction flask, then add 300 mL of 6 M hydrochloric acid and shake to dissolve the solid. Reflux the resulting mixture with stirring for 16 hours. After the reaction is complete, evaporate the mixture to dryness under reduced pressure to obtain the target product.

Synthetic Route of Aminomethylphosphonic Acid

Chemical PropertiesBack Directory
[Appearance]

white crystals or powder
[Melting point ]

300 °C
[Boiling point ]

358.0±44.0 °C(Predicted)
[density ]

0.6
[RTECS ]

SZ6526000
[storage temp. ]

0-6°C
[solubility ]

water: soluble50mg/mL, clear, colorless
[form ]

Fine Crystalline Powder
[pka]

pK1: 2.35;pK2: 5.9;pK3: 10.8 (25°C)
[color ]

White
[Stability:]

Stable. Incompatible with strong oxidizing agents. Protect from moisture.
[Water Solubility ]

soluble
[Sensitive ]

Hygroscopic
[BRN ]

1701219
[Major Application]

agriculture
environmental
[InChI]

1S/CH6NO3P/c2-1-6(3,4)5/h1-2H2,(H2,3,4,5)
[InChIKey]

MGRVRXRGTBOSHW-UHFFFAOYSA-N
[SMILES]

NCP(O)(O)=O
[CAS DataBase Reference]

1066-51-9(CAS DataBase Reference)
[EPA Substance Registry System]

1066-51-9(EPA Substance)
Safety DataBack Directory
[Symbol(GHS) ]

Exclamation Mark (GHS07)
GHS07
[Signal word ]

Warning
[Hazard statements ]

H315-H319-H335
[Precautionary statements ]

P261-P280a-P304+P340-P305+P351+P338-P405-P501a-P264-P280-P302+P352+P332+P313+P362+P364-P305+P351+P338+P337+P313
[Hazard Codes ]

Xi,C
[Risk Statements ]

R36/37/38:Irritating to eyes, respiratory system and skin .
R35:Causes severe burns.
[Safety Statements ]

S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36:Wear suitable protective clothing .
S24/25:Avoid contact with skin and eyes .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
[RIDADR ]

UN 3261 8/PG 3
[WGK Germany ]

3
[F ]

3-9
[HS Code ]

29319090
[Storage Class]

11 - Combustible Solids
Raw materials And Preparation ProductsBack Directory
[Raw materials]

Sodium hydroxide-->Hydrochloric acid-->Tetrahydrofuran-->Carbon tetrachloride-->Hydrazinium hydroxide solution-->N-Bromosuccinimide-->N,N-Dimethylaniline-->Benzoyl peroxide-->Methyl bromide-->Phthalimide-->Trimethyl phosphite
[Preparation Products]

Formaldehyde
Hazard InformationBack Directory
[Chemical Properties]

white crystals or powder
[Uses]

(Aminomethyl)phosphonic acid is used in the preparation of (acetylamino-methyl)-phosphonic acid by reacting with acetic anhydride. Further, it is used in the development of immobilized metal affinity chromatography column based on organic-inorganic hybrid silica monolith.
[Uses]

Aminomethanephosphonic acid is a degradation product of glyphosate (G765000), a herbicide.
[Definition]

ChEBI: A member of the class of phosphonic acids that is phosphonic acid substituted by an aminomethyl group. It is a metabolite of the herbicide glyphosate.
[General Description]

(Aminomethyl)phosphonic acid is a metabolite of amitrole and glyphosate herbicides and was analyzed by HPLC using an electrochemical detector.
Spectrum DetailBack Directory
[Spectrum Detail]

(Aminomethyl)phosphonic acid(1066-51-9)1HNMR
(Aminomethyl)phosphonic acid(1066-51-9)IR1
(Aminomethyl)phosphonic acid(1066-51-9)IR2
Well-known Reagent Company Product InformationBack Directory
[Acros Organics]

(Aminomethyl)phosphonic acid, 99%(1066-51-9)
[Alfa Aesar]

(Aminomethyl)phosphonic acid, 99%(1066-51-9)
[Sigma Aldrich]

1066-51-9(sigmaaldrich)
[TCI AMERICA]

(Aminomethyl)phosphonic Acid,>95.0%(T)(1066-51-9)
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