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6419-19-8

6419-19-8 Structure

6419-19-8 Structure
IdentificationMore
[Name]

Amino tris(methylene phosphonic acid)
[CAS]

6419-19-8
[Synonyms]

AMINO TRI(METHYLENE PHOSPHONIC ACID)
Aminotris(methanephosphonic acid)
AMINO, TRIS(METHYLENE PHOSPHONIC ACID)
ATMP
BRIQUEST 301-50A
Dequest 2000
NITRILOTRIMETHANEPHOSPHONIC ACID
NITRILOTRI(METHYLPHOSPHONIC ACID)
NITRILOTRIS(METHYLENEPHOSPHONIC ACID)
NITRILOTRIS(METHYLENE)TRIPHOSPHONIC ACID
TRIS(PHOSPHONOMETHYL)AMINE
(nitrilo
(nitrilotris(methylene))triphosphonic
(nitrilotris(methylene))tri-phosphonicaci
(nitrilotris(methylene))trisphosphonicacid
(nitrilotris(methylene))tris-Phosphonicacid
[nitrilotris(methylene)]tris-phosphonicaci
[nitrilotris(methylene)]trisphosphonicacid
aminotri(methylphosphonicacid)
aminotris(methylphosphonicacid)
[EINECS(EC#)]

229-146-5
[Molecular Formula]

C3H18NO9P3
[MDL Number]

MFCD00002138
[Molecular Weight]

305.1
[MOL File]

6419-19-8.mol
Chemical PropertiesBack Directory
[Appearance]

colourless liquid
[Melting point ]

~215 °C (dec.)
[Boiling point ]

746.2±70.0 °C(Predicted)
[density ]

1.3 g/mL at 25 °C
[vapor pressure ]

0Pa at 25℃
[storage temp. ]

Sealed in dry,Room Temperature
[solubility ]

Water (Slightly, Heated)
[form ]

Solid
[pka]

0.56±0.10(Predicted)
[color ]

White
[PH]

0.46
[Stability:]

Stable. Incompatible with bases, strong oxidizing agents.
[Water Solubility ]

500g/L at 20℃
[BRN ]

1715724
[Cosmetics Ingredients Functions]

CHELATING
[InChI]

1S/C3H12NO9P3/c5-14(6,7)1-4(2-15(8,9)10)3-16(11,12)13/h1-3H2,(H2,5,6,7)(H2,8,9,10)(H2,11,12,13)
[InChIKey]

YDONNITUKPKTIG-UHFFFAOYSA-N
[SMILES]

OP(O)(=O)CN(CP(O)(O)=O)CP(O)(O)=O
[LogP]

-3.5
[CAS DataBase Reference]

6419-19-8(CAS DataBase Reference)
[EPA Substance Registry System]

6419-19-8(EPA Substance)
Safety DataBack Directory
[Symbol(GHS) ]

Corrosion (GHS05)
GHS05
[Signal word ]

Warning
[Hazard statements ]

H290
[Precautionary statements ]

P234-P390
[Hazard Codes ]

Xi,C
[Risk Statements ]

R36:Irritating to the eyes.
R34:Causes burns.
[Safety Statements ]

S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S25:Avoid contact with eyes .
[RIDADR ]

3265
[WGK Germany ]

1
[RTECS ]

SZ9860000
[F ]

3-9
[TSCA ]

TSCA listed
[REACH Registrations]

Active
[HazardClass ]

8
[PackingGroup ]

III
[HS Code ]

29319090
[Storage Class]

8A - Combustible corrosive hazardous materials
[Hazard Classifications]

Met. Corr. 1
Raw materials And Preparation ProductsBack Directory
[Raw materials]

Ammonium chloride-->Phosphorus trichloride-->formaldehyde
[Preparation Products]

Chitosan
Hazard InformationBack Directory
[Chemical Properties]

colourless liquid
[Definition]

ChEBI: [Nitrilotris(methylene)]trisphosphonic acid is a phosphonoacetic acid.
[General Description]

Nitrilotris(methylene)triphosphonic acid solution is an antiscalant and can be removed form membrane concentrates by iron-coated waste filtration sand. It is a cement retarder. It reacts with the aluminum surface to form a coating which is an effective inhibitor of the reaction of evaporated aluminum thin films on glass or silicon with deionized water.
[Flammability and Explosibility]

Notclassified
[Synthesis]

(1) 15g of yellow phosphorus into the nitrogen deoxygenated closed reactor;

(2) heating to 45 ℃ to the reactor into a small amount of high purity oxygen, in the insufficient oxygen incomplete combustion, in the closed reactor to get the phosphoru

[Toxics Screening Level]

Therefore, the screening level is being established under R232(i) at 0.1 μg/m3 with annual averaging.
Questions And AnswerBack Directory
[Water treatment agent]

Amino tris(methylene phosphonic acid), its solid form is crystalline powder, soluble in water, hygroscopic, has excellent chelation, low threshold inhibition and lattice distortion. It has excellent scale inhibition below 200 ℃, low toxicity, good thermal stability, Amino tris(methylene phosphonic acid) can be dissociated into six positive and negative ions in the water, and can form a stable chelate with a variety of metal ions such as iron, copper, aluminum, zinc, calcium, magnesium, etc. It has a more preferable scale inhibition effect on carbonate . And it has good synergy with the polyphosphate, polycarboxylate, nitrite. There are good inhibition when in 40mg/L.
[Uses]

It is used for power plants, refineries, petrochemicals, fertilizer plant cooling water, oil field injection water system,particularly suitable for hard high-calcium, low concentration multiple systems, such as power plants and high hardness high salinity, bad water quality conditions of the oil pipeline inhibitors,which may decrease the risk of corrosion and scaling of metal equipment and pipeline. In the textile printing and dyeing industry,Amino tris(methylene phosphonic acid) is used as a metal ion chelating agent, metal surface treatment agent.
The above information is edited by the chemicalbook of Tian Ye.
[Instructions]

Amino tris(methylene phosphonic acid) is often used with other organic acid, polylactic acid or salt to form organic water treatment agents for circulating cooling water systems under a variety of different water quality conditions. The amount of 1~20mg/L is preferred; in an amount of 20~60mg/L when used as a corrosion inhibitor .
Amino tris(methylene phosphonic acid)is acidic, pay attention to labor protection, should avoid contact with eye and skin, once contacted, flush with plenty of water.
[Reference quality standards]

tem Index
In line with HG/T 2841-1997 in line with HG/T2841-2005
Appearance colorless or light yellow transparent liquid white crystalline powder
Active content (ATMP dollars)% ≥ 50.0 50.0 95.0
Amino tris(methylene phosphonic acid)content% ≥-40.0 88.0
Phosphite (in terms PO33-)% ≤ 5.0 3.5-
Phosphate (PO43-to count)% ≤ 1.0 0.8 0.8
Chloride (Cl-dollars)% ≤ 3.5 2.0 1.0
Iron (with Fe2 +) content mg/L ≤-20.0 20.0
Density (20 ℃) g/cm3 ≥ 1.28 1.30- pH (1% aqueous solution) 1.5-2.5 1.5-2.5 2.0
[Usage]

Used for the scale prevention of cooling water system, oil pipeline and boiler; Used as the scale inhibitor for the oil pipeline with high hardness, high salinity and bad water quality; Used as scale inhibitor and corrosion inhibitor for the treatment of cooling water, boiler water, oil field water; Used for circulating cooling water of thermal power plant and an oil refinery.
Spectrum DetailBack Directory
[Spectrum Detail]

Amino tris(methylene phosphonic acid)(6419-19-8)1HNMR
Amino tris(methylene phosphonic acid)(6419-19-8)IR
Amino tris(methylene phosphonic acid)(6419-19-8)Raman
Well-known Reagent Company Product InformationBack Directory
[Acros Organics]

Nitrilotris(methylene)triphosphonic acid, 50 wt% solution in water(6419-19-8)
[Sigma Aldrich]

6419-19-8(sigmaaldrich)
[TCI AMERICA]

Nitrilotris(methylenephosphonic Acid)  (ca. 50% in Water, ca. 2.2mol/L)(6419-19-8)
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